Synthesis of Dibenzoxepine Lactams via a Cu-Catalyzed One-Pot Etherification/Aldol Condensation Cascade Reaction: Application toward the Total Synthesis of Aristoyagonine
[2013]
Lim, Hye Sun
Choi, Young Lok
Heo, Jung-Nyoung
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Synthesis of Dibenzoxepine Lactams via a Cu-Catalyzed One-Pot Etherification/Aldol Condensation Cascade Reaction: Application toward the Total Synthesis of Aristoyagonine
2013
Lim, Hye Sun; Choi, Young Lok; Heo, Jung-Nyoung
http://dx.doi.org/10.1021%2Fol402036t
A general synthesis of dibenzoxepine lactams has been developed using a one-pot Cu-catalyzed etherification/aldol condensation cascade reaction. The reaction of 4-hydroxyisoindolin-1-one with a wide range of 2-bromobenzaldehydes in the presence of a copper catalyst provided various aristoyagonine derivatives in good yields.
[lactams, catalysts, condensation reactions, copper, chemical structure]
[Organic letters]
2018/US/US2018_3.rdf
摘要
A general synthesis of dibenzoxepine lactams has been developed using a one-pot Cu-catalyzed etherification/aldol condensation cascade reaction. The reaction of 4-hydroxyisoindolin-1-one with a wide range of 2-bromobenzaldehydes in the presence of a copper catalyst provided various aristoyagonine derivatives in good yields.
其它题目
lactams
catalysts
condensation reactions
copper
chemical structure
学术期刊
Organic letters
ISSN
:
1523-7052
其他信息
语言
:
English
类型
:
Journal Article
In AGRIS since
:
2018
卷
:
15
期
:
18
程度
:
4718-4721
出版者
:
American Chemical Society
所有题名
:
"
Synthesis of Dibenzoxepine Lactams via a Cu-Catalyzed One-Pot Etherification/Aldol Condensation Cascade Reaction: Application toward the Total Synthesis of Aristoyagonine
"