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The European Union is a unique economic and political union between 27 EU countries. The goals of the European Union are: - promote peace, its values and the well-being of its citizens - offer freedom, security and justice without internal borders - sustainable development based on balanced economic growth and price stability, a highly competitive market - - - economy with full employment and social progress, and environmental protection - combat social exclusion and discrimination - promote scientific and technological progress - enhance [...]

Journal Article

Artículo de revista

Structure elucidation of some proanthocyanidins in barley by 1H 270 MHz NMR spectroscopy [anthocyanogens, chromatography, procyanidin, prodelphinidin]  [1981]

Outtrup, H.; Schaumburg, K.; Carlsberg Lab., Copenhagen (Denmark) [Corporate Author]

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In the present paper the composition of proanthocyanidins isolated from barley is investigated. Separation by affinity chromatography and HPLC yields a large number of substances. Six of these have been isolated in this work. Based on the chromatographic preparation they are expected to be two dimers D1 and D2 and four trimeric substances T1 - T4. Studies by means of ('1)H NMR spectroscopy at 270 MHz confirmed D1 and D2 as being dimeric compounds, a prodelphinidin and procyanidin B(,3) respectively. The spatial structure of the prodelphinidin corresponds to procyanidin B(,3). The peracetates of all six compounds have also been studied by means of ('1)H NMR spectroscopy. By comparison with data for the analogous peracetates of (+)-catechin and (-)-epicatechin and with literature data, T1 - T4 have been identified as trimeric proanthocyanidins and their structures have been elucidated

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Información bibliográfica

Idioma:
English
Tipo:
Summary
En AGRIS desde:
1982
Volumen:
46
Edición:
1
Página inicial:
43
Página final:
52
Todos los títulos:
" Structure elucidation of some proanthocyanidins in barley by 1H 270 MHz NMR spectroscopy [anthocyanogens, chromatography, procyanidin, prodelphinidin] "
Otro:
" 4 ill., 17 ref. Summary (En) "

Publicación

Carlsberg Research Communications (Denmark)

ISSN : 0105-1938