Macro- and micro-elements in bottled and tap waters in Serbia | Makro- i mikroelementi u flaširanim vodama i vodama iz javnih vodovoda u Srbiji

Comparative analysis between bottled and tap waters as well as its comparison with current Serbian regulations, European Union Directives and World Health Organization standard are shown in this paper. Thirteen bottled waters and fourteen tap waters from the territory of Serbia were analyzed in the Federal Institute for Geosciences and Natural Resources (BGR) laboratory in Berlin, for the purpose of the Geochemistry of European Bottled Water project conducted by EuroGeo Survey Geochemistry (EGS). Macrocomponents (main cations and anions) of ground waters usually reflect on lithogeochemistry of the aquifer, while microcomponents indicate the circulation of ground water through the different lithological environment. Analyzed bottled waters could be classified as those with low mineral content (M is less than 500 mg/l) if HCO3 anion and Ca and Mg cations were the prevailing ones, or mineral (M is greater than 500 mg/l) with prevailing HCO3– and Na+. Waters with low mineral content were mainly from limestone and dolomite, while mineral waters mainly originated from magmatic and metamorphic rocks. Higher content of Cs, Li, Ge, Rb and F in bottled waters indicates the importance of the magmatic intrusions influence on their chemical composition. In some waters higher content of B, I, NH4, as well as of Tl and W has been observed which can be attributed to water circulation through different lithological complexes. Tap water was mostly obtained from groundwater (from Neogen and alluvial aquifers and karst springs) with rest being those of rivers and surface accumulations. Tap waters from Central Serbia were with low mineral content, with prevailing HCO3– and Ca and Mg cations, while waters from Vojvodina, the northern province of Serbia, were with higher mineralization, HCO3–Na. Chemical analyses of the sampled tap waters showed good quality, with exception of waters from the cities of Senta and Zrenjanin in Vojvodina. High values of B (1170 and 895 microg/l), As (20.9 and 71.9 microg/l), Na (208 and 275 mg/l), as well as EC (715 and 928 microS/cm) have been registered in these waters.