On-line speciation of arsenical compounds in fish and mussel extracts by HPLC-ICP-MS
1994
Caroli, S. (Istituto Superiore di Sanita, Rome (Italy)) | La Torre, F. | Petrucci, F. | Violante, N.
The separation and determination of sub-micromol per litre levels of six environmentally significant As compounds was accomplished by means of high performance liquid chromatography (HPLC) combined online with inductively coupled plasma mass spectrometry (ICP-MS). The species of interest (arsenite and arsenate, monomethylarsonic acid, dimethylarsinic acid, arsenobetaine and arsenocholine) were quantified in fish and mussel extracts after separation on a Dionex AS7 column equipped with an on-guard AG7 column using a bicarbonate buffer as the mobile phase in a gradient mode. The species thus eluted were directly forwarded to the ICP-MS detector. The detection power of the overall system allows each As form to be determined at concentrations as low a 0.0013 - 0.0027 micromol per litre.
اظهر المزيد [+] اقل [-]الكلمات المفتاحية الخاصة بالمكنز الزراعي (أجروفوك)
المعلومات البيبليوغرافية
تم تزويد هذا السجل من قبل ZB MED Nutrition. Environment. Agriculture
