Preparation of solid organic fertilizer by co-hydrothermal carbonization of peanut residue and corn cob: A study on nutrient conversion

With continuous recognition of green, organic and pollution-free products, the organic fertilizer plays an increasingly important role in agricultural production. Hydrothermal carbonization (HTC) is an efficient and environmentally friendly biomass treatment technology that can achieve value-added utilization of solid wastes. This study evaluated the potential of two typical agricultural and forestry wastes (corn cob and peanut residue) in preparing as solid organic fertilizers through HTC. The effects of reaction temperature, residence time, and the raw material composition on hydrochar yield, total nutrient content (TNC), nitrogen recovery, and nutrient elements transformation in HTC were investigated. Corn cob was proven to be not an ideal raw material for the preparation of organic fertilizers because of the low TNC and the high C/N ratio of its hydrochar. On the contrary, peanut residue was suitable for preparing organic fertilizers due to its high TNC and appropriate C/N ratio. The co-HTC of corn cob and peanut residue could further improve the N recovery rate from 8.52% (for peanut residue only) to 19.51% due to the synergistic effect between them. Under the optimal hydrothermal conditions of 240 °C, 120 min, and mixing ratio of 1:1, the hydrochar yield was as high as 27.86%, and the C/N value (11.98) and TNC (6.331%) were both appropriate as fertilizer. Furthermore, the potential migration and transformation paths of nutrients including N, P, K and metal elements in the co-HTC were analyzed. The thermodynamic conditions and raw materials composition significantly affect the migration and transformation of N, P and K between solid and liquid. N dissolved into process water (mainly ammonia) would migrate into hydrochar and bio-oil with increasing of reaction temperature. P was fixed in hydrochar through precipitation and adsorption reaction with metal ions. Further, adjusting pH or adding metal salts can promote the fixation of N and P in solid.