Development of an activated carbon impregnation process with iron oxide nanoparticles by green synthesis for diclofenac adsorption

Silveira, Carole; Shimabuku-Biadola, Quelen Letícia; Silva, Marcela Fernandes; Vieira, Marcelo Fernandes; Bergamasco, Rosângela

Development of an activated carbon impregnation process with iron oxide nanoparticles by green synthesis for diclofenac adsorption

2020

Silveira, Carole | Shimabuku-Biadola, Quelen Letícia | Silva, Marcela Fernandes | Vieira, Marcelo Fernandes | Bergamasco, Rosângela

The objective of this study was to impregnate the surface of palm coconut activated carbon with nanoparticles of iron compounds using Moringa oleifera leaf extracts and pomegranate leaf by a green synthesis method and to evaluate its adsorption capacity for sodium diclofenac. The adsorbent material was characterized by zeta potential, X-ray diffraction (XRD), N₂ adsorption/desorption (BET method), transmission electronic microscopy (TEM), and scanning electronic microscopy (SEM) coupled to dispersive energy spectrometry X-ray (EDX) methods. To evaluate the adsorption capacity of sodium diclofenac, the influence of pH, kinetics, isotherms, and thermodynamic properties were analysed. The impregnated adsorbents showed efficiency in the adsorption of sodium diclofenac. The kinetic model that best fit the experimental data was the pseudo-second-order model, and the equilibrium model was the Langmuir model. As for the thermodynamic study, it was verified that the adsorption reaction for all adsorbents occurs in a spontaneous, favourable way, and it is endothermic by physisorption. Therefore, this process is promising because it is a clean and non-toxic method when compared with chemical methods for the synthesis of nanoparticles.

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