Seasonal variations of imidazoles in urban areas of Beijing and Guangzhou, China by single particle mass spectrometry

Imidazoles (IMs) are potential contributors to brown carbon; they may notably contribute to climate radiative forcing. However, only a few studies have assessed the mixing state, seasonal and spatial distributions of IMs, and influencing factors for IM formation in urban aerosols. In this study, two single-particle aerosol mass spectrometers were employed to investigate the IM-containing particles in the urban areas of Beijing and Guangzhou, China. IM-containing particles were identified in the size range (dᵥₐ) of 0.2–2.0 μm, accounting for 0.7–21.7 % of all the detected particles. The number fractions of IM-containing particles in both cities were the lowest in winter and the highest in spring, probably owing to the difference in the abundance of precursors and the particle acidity. Majority of (60–80 % by number) the IM-containing particles were mixed with organic carbon (OC), with the lowest fractions found in summer. Although the number fractions of IM-containing particles in Beijing were generally higher (~1.5–3 times) than those in Guangzhou, the mixing states of the IM-containing particles at these two sites were only slightly different. Potassium-rich (K-rich) and potassium-sodium (KNa) particles were rarely found in Guangzhou; they accounted for ~15 % of the IM-containing particles in Beijing. Additionally, our results indicate that particles with higher acidity are favorable for IM formation. These findings help improving our knowledge of the mixing state, seasonal variation, and spatial distribution of IMs in urban aerosols, and the insights in influencing factors into IM formation provide valuable information for future studies of the atmospheric chemical processes associated with IMs.