Morphology and thermal properties of copolymer based on p-aminobenzonitrile type benzoxazine and diglycidyl ether of bisphenol-A
2013
Liu, Yanfang | Zhang, Jie | Liao, Chunyan | Zheng, Junfeng | Zhao, Shasha | Run, Mingtao
A copolymer of p-aminobenzonitrile type benzoxazine (BA-pabn) and diglycidyl ether of bisphenol-A (DGEBA) was prepared. With rising DGEBA content, the peak temperature of the differential scanning calorimetry curve for polymerization of BA-pabn/DGEBA blend shifts to higher value, and the roughness of the fracture surface of the BA-pabn/DGEBA copolymer increases. In the glassy state, the storage modulus of the copolymer initially tends to increase with rising DGEBA content over pure polybenzoxazine (PBA-pabn), but decreases when DGEBA content reaches to 50wt%. The copolymer exhibits a single glass transition temperature lower than that of PBA-pabn. The onset weight loss temperature of the copolymer is higher than that of PBA-pabn, but the char yield at 800°C is lower.
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