Regio-defined syntheses of tetra-brominated dibenzo[g,p]chrysene scaffolds with high solubility
2021
Fujii, Yoshino | Maruyama, Tomoyuki | Akasaka, Ryuhei | Sakao, Kazuki | Tokai, Shugo | Taguchi, Yuta | Matsumoto, Yasuhiro | Kamiguchi, Shinsuke | Yoshida, Naoki | Iwasawa, Tetsuo
Regio-defined syntheses of tetra-brominated dibenzo[g,p]chrysene (DBC) derivatives are described, with a description of different patterns of the four-bromine-positions. These derivatives were designed with two features: one is installation of butyl groups for being processable in solution-phase, and the other is attachment of bromine atoms for being variable. Thus, these brominated devices would enable us to achieve diversity-oriented preparation of solution-processable DBC derivatives.
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