Moisture in softwoods: fiber saturation point, hydroxyl site content, and the amount of micropores as determined from NMR relaxation time distributions
2012
Distributions of nuclear magnetic resonance (NMR) relaxation times provide detailed information about the moisture absorbed in wood. In this work, T₂*, T₂, and T₁ distributions were recorded from fresh sapwood and heartwood samples of pine (Pinus sylvestris) and spruce (Picea abies) at various temperatures. Below the melting point of bulk water, free water is frozen and its signal disappears from the distributions. Then, the low-temperature distributions of the unfrozen bound water contain more information about its components, because the large free water peaks hiding some smaller bound water peaks are absent and the exchange between free and bound water is prevented. Comparison of the total moisture signal integrals above and below the bulk melting point enables the determination of fiber saturation point (FSP), which, in this context, denotes the total water capacity of cell wall. T₂*, T₂, and T₁ distributions offer different kinds of information about moisture components. All the peaks in the distributions were assigned, and it was demonstrated that the accessible hydroxyl site content and the amount of micropores can be estimated based on the peak integrals.
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