Sustainable Treatment of Antibiotic Wastewater Using Combined Process of Microelectrolysis and Struvite Crystallization

Zhang, Jishi; Chen, Shujun; Wang, Xikui

Sustainable Treatment of Antibiotic Wastewater Using Combined Process of Microelectrolysis and Struvite Crystallization

2015

Zhang, Jishi | Chen, Shujun | Wang, Xikui

The aim of this study was to investigate the synergistic effects of the process of iron-carbon microelectrolysis (ICME) followed by struvite (MAP) crystallization on treating antibiotic wastewater. Characteristics of ICME effluent depended mainly on the iron to carbon mass ratio (Fe/C). The optimum reaction conditions of Fe/C ratio of 2:1 and reaction time of 90 min were observed. The ICME effluent was further treated by MAP crystallization using Na₂HPO₄·12H₂O and MgCl₂·6H₂O as precipitation agents. The results showed that, the Mg²⁺/NH₄ ⁺-N/PO₄ ³⁻-P molar ratio of 1:1:1 and pH 8.5, were suitable for the crystallization process, which could obtain high-quality MAP containing 5.18 % N,10.23 % Mg, and 13.83 % P. Optimal total removal rate of COD and NH₄ ⁺-N removal rate achieved 84.6 and 89.9 %, respectively. The economic evaluation of NH₄ ⁺-N recovery by the synergistic process was also conducted, indicating that the synergistic process had the potential to benefit COD emission reduction and nitrogen recovery. Graphical Abstract The aim of this study was to investigate the effects of treating antibiotic wastewater using iron and carbon combined process of microelectrolysis and struvite (MAP) crystallization. The MAP was of high purity and good crystal morphology, which could be used as a slow-release fertilizer.

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