Key role of NO + C3H8 reaction for the elimination of NO in automobile exhaust by three-way catalyst
2019
Chen, Yusheng | Deng, Jie | Fan, Jun | Jiao, Yi | Wang, Jianli | Chen, Yaoqiang
Pd-only three-way catalysts with improved catalytic activity for NO elimination were prepared. In order to explore the catalytic reaction rules of NO reduction under a three-way catalytic system, a series of single reactions related to NO reduction were evaluated. It was found that the reaction temperatures of NO + H₂ or NO + CO or NO + C₃H₆ reactions were below 250 °C, while that of NO + C₃H₈ was up to 350 °C. Thus, the reaction NO + C₃H₈ served as the key reaction in determining the purification efficiency of NO at the high-temperature stage. By in situ FTIR, we proposed that three possible steps were involved in NO + C₃H₈ reaction. The first step was the oxidation of C₃H₈ and NO to acetone and nitrate species by active oxygen species, respectively (C₃H₈ + O* → C₃H₆O, NO + O* → NO₃⁻). XPS results revealed that the amount of active oxygen species in Pd/CeO₂-ZrO₂-Al₂O₃ (Pd/CZA, 73.7%) was much higher than that in Pd/CeₓZr₁₋ₓO₂+Al₂O₃ (Pd/CZ+A, 64.1%). This was in line with the higher reaction efficiency of the first step over Pd/CZA. Then the NO + C₃H₈ reaction was accelerated by the first step, which consequently contributed to the higher NO elimination efficiency of Pd/CZA.
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