Mechanisms of Electrotunable Friction in Friction Force Microscopy Experiments with Ionic Liquids
2018
Pivnic, Karina | Fajardo, Oscar Y. | Bresme, Fernando | Kornyshev, A. A. (Alexei A.) | Urbakh, Michael
Using molecular dynamics simulations and a coarse-grained model of ionic liquids (ILs), we study mechanisms of electrotunable friction measured in friction force microscopy experiments, where only one layer of IL is present between the tip and the electrode (substrate). We show that the variation of the friction force with the electrode surface charge density is determined by the regime of motion of the confined IL relative to the substrate and tip. The latter depends on the strengths of the ion–substrate and ion–tip interactions and on the commensurability between the characteristic ion dimensions and lattice spacings of the substrate and tip surfaces. Related with those factors, our simulations predict two strictly different scenarios for the variation of the friction force with the electrode surface charge. Revealing mechanisms of frictional energy dissipation in nanoscale IL films offers a way for controlling friction by tuning ion–substrate interactions and electrical polarization of sliding surfaces.
اظهر المزيد [+] اقل [-]الكلمات المفتاحية الخاصة بالمكنز الزراعي (أجروفوك)
المعلومات البيبليوغرافية
تم تزويد هذا السجل من قبل National Agricultural Library