A straightforward synthesis of visible light driven BiFeO3/AgVO3 nanocomposites with improved photocatalytic activity

Bavani, Thirugnanam; Madhavan, Jagannathan; Prasad, Saradh; AlSalhi, Mohamad S.; AlJaafreh, Mamduh J.

A straightforward synthesis of visible light driven BiFeO3/AgVO3 nanocomposites with improved photocatalytic activity

2021

Bavani, Thirugnanam | Madhavan, Jagannathan | Prasad, Saradh | AlSalhi, Mohamad S. | AlJaafreh, Mamduh J.

Herein, an efficient visible-light-driven BiFeO₃/AgVO₃ nanocomposite was effectively fabricated via a facile co-precipitation procedure. The physicochemical properties of BiFeO₃/AgVO₃ nanocomposites were investigated via Fourier transform-infrared (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL), UV visible diffuse reflectance spectroscopy (DRS) and photoelectrochemical studies (PEC). The photocatalytic activity (PCA) of BiFeO₃/AgVO₃ nanocomposites was assessed with regard to the photocatalytic degradation of Rhodamine-B (RhB) when subjected to visible light irradiation (VLI). Upon 90 min of illumination, the optimal 3%-BiFeO₃/AgVO₃ nanocomposite showed a greater photocatalytic degradation, which was ∼3 times higher than the bare AgVO₃. The lower PL intensity of 3%-BiFeO₃/AgVO₃ nanocomposite exposed the low recombination rate, which improved the photo-excited charge carriers separation efficiency. The experimental outcomes showed that the BiFeO₃/AgVO₃ nanocomposite might be an encouraging material for treatment of industrial and metropolitan wastewater. Moreover, a plausible RhB degradation mechanism was proposed proving the participation of the generated OH and O₂– radicals in the degradation over BiFeO₃/AgVO₃ nanocomposite.

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