Charge separation effect in the nanocomposites of Co3O4-QDs: visible light photocatalytic dye degradation in aqueous solutions
2022
Masteri-Farahani, Majid | Mosleh, Nazanin | Ramzi, Sajedeh
Photo-treatment of water is a promising environmentally friendly process that provides clean water and makes wastewater reusable in industry. Thus, efforts toward finding highly efficient photocatalysts have gained a huge attention to remove the organic contaminants in water. Quantum dots (QDs) are extensively utilized for photocatalytic remediation regarding their prominent optical, electrical, and chemical properties. Herein, we report the highly efficient and environmentally friendly synthesis of Co₃O₄-QDs-based graphene quantum dots (GQDs) and infinite coordination polymer comprising Zn nodes (Zn-ICP) nanocomposites as active and robust photocatalysts for photo-assisted water treatment. The pristine Co₃O₄-QDs, GQDs, and Zn-ICP showed lower activity under visible light. However, after functionalization of GQDs and Zn-ICP with Co₃O₄-QDs, the activity increased, and more photocatalytic efficiency was achieved. For instance, Zn-ICP, GQDs, Co₃O₄-QDs, Co₃O₄-QDs/Zn-ICP, and Co₃O₄-QDs/GQD degraded 21, 19, 52, 73, and 83% of rhodamine B (RhB) and 34, 46, 50, 73, and 76% of methylene blue (MB) after 60 min. The high photocatalytic efficiency was ascribed to the conjugation of Co₃O₄-QDs with GQDs and Zn-ICP which causes efficient absorption of visible light. The existence of Co₃O₄-QDs was found to be essential not only for effective charge separation but also widening the region of light absorption followed by increase in photocatalytic performances. Charge separation in photocatalytic reactions, energy levels of nanocomposites, and mechanism of the photocatalytic process were investigated by photoluminescence spectra (PL), Mott-Schottky, electrochemical impedance (EIS), and diffuse reflectance UV–Vis spectroscopy (DRS).
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