Thermostabilität von Vinylmagnesiumchlorid in Tetrahydrofuran / Thermal Stability of Vinylmagnesium Chloride in Tetrahydrofuran
2014
Rittmeyer, P. | Hauk, D.
An incident at Chemetall’s pilot plant installation during the distillation of dilute solutions of vinylmagnesium chloride in THF caused us to investigate the thermal stability of this Grignard reagent. The on-set temperature for the exothermic decomposition depends on the concentration of the solution. Experiments under isoperibolic conditions provided further information for the determination of safety rules for work with vinylmagnesium chloride.
اظهر المزيد [+] اقل [-]الكلمات المفتاحية الخاصة بالمكنز الزراعي (أجروفوك)
المعلومات البيبليوغرافية
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