Distribution of Road Salt Residues, Heavy Metals and Polycyclic Aromatic Hydrocarbons across a Highway-Forest Interface

Zehetner, Franz; Rosenfellner, Ulrike; Mentler, Axel; Gerzabek, Martin H.

Distribution of Road Salt Residues, Heavy Metals and Polycyclic Aromatic Hydrocarbons across a Highway-Forest Interface

2009

Zehetner, Franz | Rosenfellner, Ulrike | Mentler, Axel | Gerzabek, Martin H.

Automobile traffic pollutes roadside environments with a range of contaminants. In this study, we investigate the distribution patterns of different contaminant classes in topsoils across a highway-forest interface north-east of Vienna, Austria, in order to assess spatial pollutant distribution and evaluate the filtering effect of roadside forests. We collected soil samples along transects perpendicular to the highway, and analyzed the soils for road salt residues (Na), total and mobile heavy metals (Pb, Cd, Cu, Zn, Ni, Cr) as well as polycyclic aromatic hydrocarbons (PAHs). Roadside soil pollution was highly heterogeneous. All contaminants followed an exponential-like decrease with distance from the road, reaching background levels at 5 to 10 m from the road curb. Traffic-born heavy metals in the immediate roadside zone tended to be more mobile than heavy metals of predominantly geogenic origin at greater distances from the road; the presence of road salt residues could have contributed to the elevated heavy metal mobility near the road. The forest vegetation acted as filter for PAHs shown by a sharp concentration increase at the forest edge. PAHs are likely transported with airborne soot particles that are scavenged by the wax-coated coniferous needles at our study site.

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