Total synthesis of α-1-C-propyl-3,6-di-epi-nojirimycin and polyhydroxyindolizidine alkaloids via regio- and diastereoselective amination of anomeric acetals
2022
Kim, Yeon Su | Boggu, Pulla Reddy | Kong, Younggyu | Park, Gi Min | Kim, In-su | Jung, Young-Hoon
The synthesis of α-1-C-propyl-3,6-di-epi-nojirimycin and Polyhydroxyindolizidine alkaloids from readily available α-methyl-d-mannopyranoside is described. The key step in this process involves a regioselective and diastereoselective amination of anomeric acetal functionality using chlorosulfonyl isocyanate (CSI).
اظهر المزيد [+] اقل [-]الكلمات المفتاحية الخاصة بالمكنز الزراعي (أجروفوك)
المعلومات البيبليوغرافية
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