Recycling of iron and silicon from drinking water treatment sludge for synthesis of magnetic iron oxide@SiO2 composites

Meng, Lingyou; Chan, Yingzi; Wang, Han; Dai, Ying; Wang, Xue; Zou, Jinlong

Recycling of iron and silicon from drinking water treatment sludge for synthesis of magnetic iron oxide@SiO2 composites

2016

More attention has been paid to the deterioration of water bodies polluted by drinking water treatment sludge (DWTS) in recent years. It is important to develop methods to effectively treat DWTS by avoiding secondary pollution. We report herein a novel investigation for recovery of Si and Fe from DWTS, which are used for the synthesis of two iron oxide@SiO₂ composites for adsorption of reactive red X-3B (RRX-3B) and NaNO₂. The results show that Fe³⁺ (acid-leaching) and Si⁴⁺ (basic-leaching) can be successfully recovered from roasted DWTS. Whether to dissolve Fe(OH)₃ precipitation is the key point for obtaining Fe₃O₄ or γ-Fe₂O₃ particles using the solvothermal method. The magnetic characteristics of Fe₃O₄@SiO₂ (390.0 m² g⁻¹) or Fe₂O₃@SiO₂ (220.9 m² g⁻¹) are slightly influenced by the coated porous SiO₂ layer. Peaks of Fe–O stretching vibration (580 cm⁻¹) and asymmetric Si–O–Si stretching vibrations (1080 cm⁻¹) of Fe₃O₄@SiO₂ indicate the successful coating of a thin silica layer (20–150 nm). The adsorption capacity of RRX-3B and NaNO₂ by Fe₃O₄@SiO₂ is better than that of Fe₂O₃@SiO₂, and both composites can be recycled through an external magnetic field. This method is an efficient and environmentally friendly method for recycling DWTS.

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