Fabrication and Characterization of Biodegradable Composite Films Made of Using Poly(caprolactone) Reinforced with Chitosan

Sharmin, Nusrat; Khan, Ruhul A.; Salmieri, Stephane; Dussault, Dominic; Lacroix, Monique

Fabrication and Characterization of Biodegradable Composite Films Made of Using Poly(caprolactone) Reinforced with Chitosan

2012

Sharmin, Nusrat | Khan, Ruhul A. | Salmieri, Stephane | Dussault, Dominic | Lacroix, Monique

Chitosan was dissolved in 2Â % aqueous acetic acid solution and the films were prepared by solution casting. Values of tensile strength (TS), tensile modulus (TM), elongation at break (EbÂ %) and water vapor permeability (WVP) of the chitosan films were found to be 30Â MPa, 450Â MPa, 8Â % and 4.7Â gÂ mm/m2Â dayÂ kPa, respectively. Poly(caprolactone) (PCL) films were prepared from its granules by compression molding and the values of TS, TM, Eb and WVP were 14Â MPa, 220Â MPa, 70Â % and 1.54Â gÂ mm/m2Â dayÂ kPa, respectively. PCL was reinforced with chitosan films, and composite films were prepared by compression molding. Amount of chitosan in the composite films varied from 10 to 50Â % (w/w). It was found that with the incorporation of chitosan films in PCL, both the values of TS and TM of composite films increased significantly. The highest mechanical properties were found at 50Â % (w/w) of chitosan content. The Oxygen transmission rate (OTR) of composite film was found to decrease significantly than PCL films. Thermal properties of the composite were also improved as compared to PCL. The water uptake test of the composite also showed promising results with a good stability of composite films. The interface of the composite was investigated by scanning electron microscopy and showed good interfacial adhesion between PCL and chitosan films.

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