Efficient Splitting of CO2 in an Isothermal Redox Cycle Based on Ceria
2014
Venstrom, Luke J. | De Smith, Robert M. | Hao, Yong | Haile, Sossina M. | Davidson, Jane H.
An isothermal thermochemical cycle to split CO₂ based on nonstoichiometric reduction and oxidation of ceria is demonstrated. Carbon monoxide is produced via an oxygen partial pressure swing by alternating inert sweep gas and CO₂ flows over the ceria. The rates of reduction and oxidation at 1500 °C in a porous ceria particle bed are measured for sweep gas and CO₂ flow rates from 50 to 600 mL min–¹ g–¹ and analyzed to identify cycle operating conditions (gas flow rates and reduction and oxidation durations) that maximize process efficiency. For a solar reactor assumed to operate at 3000 suns concentration and with 90% of the sensible heat of the gases recovered, the optimal cycle uses 150 mL min–¹ g–¹ sweep gas and 50 mL min–¹ g–¹ CO₂ at reduction and oxidation periods of 100 and 155 s, respectively. This cycle is demonstrated in an IR imaging furnace over 102 cycles, yielding a stable average rate of CO production of 0.079 μmol s–¹ g–¹ and a projected reactor efficiency of 4%. The optimal conditions apply at large scale if the flow rates are scaled in proportion to the ceria mass.
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