Solar photocatalysis as strategy for on-site reclamation of agro-wastewater polluted with pesticide residues on farms using a modular facility

Garrido, Isabel; Fenoll, José; Flores, Pilar; Hellín, Pilar; Pérez-Lucas, Gabriel; Navarro, Simón

Solar photocatalysis as strategy for on-site reclamation of agro-wastewater polluted with pesticide residues on farms using a modular facility

2021

One of the consequences of phytosanitary treatments applied to crops is the generation of a great volume of agro-wastewater having pesticide residues. These pollutants can be considered a serious threat to the environment and human health due to their capacity to affect distant areas remaining for a long time after their application. We have assessed the degradation of five pesticides in agro-waste water produced in two farms by the cleaning pesticide containers and phytosanitary treatment equipment used in the farms. For this purpose, a pilot facility was installed in both farms and advanced oxidation treatments were conducted using natural sunlight by means of Na₂S₂O₈ and heterogeneous photocatalysis (TiO₂/Na₂S₂O₈). The remaining percentages obtained at the end of the experiments ranged from 5 to 90.1% for chlorantraniliprole, 5 to 82.3% for difenoconazole, 0.02 to 19.1% for metalaxyl, 1.4 to 74.4% for myclobutanil, and 0.3 to 61% for triadimenol. We observed a correlation between the higher remaining percentages and the total initial concentration of pollutant because of other commercial formulations applied in the farms. The results showed that this equipment could be used to eliminate or reduce the presence of pesticide residues in agro-waste water using an innovative facility installed in the farms and a renewable and economical source of energy (sunlight).

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