Adaption and use of a quadcopter for targeted sampling of gaseous mercury in the atmosphere
2018
Black, Oscar | Chen, Jingjing | Scircle, Austin | Zhou, Ying | Cizdziel, JamesV.
We modified a popular and inexpensive quadcopter to collect gaseous mercury (Hg) on gold-coated quartz cartridges, and analyzed the traps using cold vapor atomic fluorescence spectrometry. Flight times averaged 16 min, limited by battery life, and yielded > 5 pg of Hg, well above the limit of detection (< 0.2 pg). We measured progressively higher concentrations upon both vertical and lateral approaches to a dish containing elemental Hg, demonstrating that the method can detect Hg emissions from a point source. Using the quadcopter, we measured atmospheric Hg near anthropogenic emission sources in the mid-south USA, including a municipal landfill, coal-fired power plant (CFPP), and a petroleum refinery. Average concentrations (± standard deviation) immediately downwind of the landfill were higher at ground level and 30 m compared to 60 and 120 m (5.3 ± 0.5 ng m⁻³, 5.4 ± 0.7 ng m⁻³, 4.2 ± 0.7 ng m⁻³, and 2.5 ± 0.3 ng m⁻³, respectively). Concentrations were also higher at an urban/industrial area (Memphis) (3.3 ± 0.9 ng m⁻³) compared with a rural/background area (1.5 ± 0.2 ng m⁻³). Due to airspace flight restrictions near the CFPP and refinery, we were unable to access near-field (stack) plumes and did not observe differences between upwind and downwind locations. Overall, this study demonstrates that highly maneuverable multicopters can be used to probe Hg concentrations aloft, which may be particularly useful for evaluating Hg emissions from remote landscapes and transient sources that are inadequately characterized and leading to uncertainties in ecosystem budgets.
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