Water content quantification by FTIR in carboxymethyl cellulose food additive

Consumi, Marco; Leone, Gemma; Tamasi, Gabriella; Magnani, Agnese

Water content quantification by FTIR in carboxymethyl cellulose food additive

2021

Consumi, Marco | Leone, Gemma | Tamasi, Gabriella | Magnani, Agnese

Water content quantification of raw polysaccharide materials for food processing is generally performed by gravimetric analysis or titrimetric methods, which are time- and energy-consuming, non-eco-friendly and sample destructive. The present study develops and validates a new approach, based on the use of Fourier transform infrared (FTIR) spectroscopy, resulting in a model of the water content of carboxymethyl cellulose (CMC) polysaccharides. Samples of CMC were exposed to different relative humidity conditions. Water content was determined by standard gravimetric methods (OIV-Oeno 404–2010) and compared with the area of FTIR absorption in the range 3675–2980 cm⁻¹, attributed to the stretching of OH groups. The strong correlation between gravimetric results and FTIR area (R² = 0.88) showed no signs of bias across the water content range. A cross-validation technique to predict the water content by band area was assessed obtaining a general equation: y = 2.12 x + 2.80 with a high repetitively and good prediction of the tested models.

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