Differential Sorption Behavior of Cadmium, Lead, Zinc, and Copper in Some Tropical Soils and Their Environmental Implications

Oladipupo Azeez, Jamiu; Olabisi Hassan, Adenike; Blessing Olowoboko, Toyin

Differential Sorption Behavior of Cadmium, Lead, Zinc, and Copper in Some Tropical Soils and Their Environmental Implications

2018

Oladipupo Azeez, Jamiu | Olabisi Hassan, Adenike | Blessing Olowoboko, Toyin

This study evaluated cadmium (Cd), lead (Pb), zinc (Zn), and copper (Cu) sorption characteristics of three tropical soils. Data obtained conformed to Freundlich sorption model and the S-shaped isotherm curve. Sorption efficiency of Zn and Pb were highest in alkaline soil while slightly acid soil had the highest Cd and Cu sorption efficiency for monometal sorption. In competitive sorption, metals were more sorbed in slightly acid soil while the least efficiency was recorded in acid soil. Distribution coefficient; Kd (average across soil types) in monometal sorption followed the order: Pb > Zn > Cd > Cu. For competitive sorption, the order was Zn > Pb > Cu > Cd. When in competition, Cd was preferentially sorbed in slightly acid and alkaline soils and Zn for acid soil. Conclusively, lead is more in equilibrium solution when in competition with Cd, Zn and Cu making it potential agent of soil and groundwater pollution.

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