Carbon material–immobilized ionic liquids were applied on absorption of Hg2+ from water phase

Sun, Lihan; Wang, Mengru; Li, Wei; Luo, Sha; Wu, Yan; Ma, Chunhui; Liu, Shouxin

Carbon material–immobilized ionic liquids were applied on absorption of Hg2+ from water phase

2020

In this study, several immobilized ionic liquid adsorbents on carbon materials were synthesized with impregnation method. The carrier materials were activated carbon and three kinds of multi-walled carbon nanotubes. And the synthetic adsorbents immobilized different kinds of ionic liquids were characterized by Boehm titration, FT-IR, XPS, TG, and BET analysis, respectively. Finally, carbon materials after [C4mim]HSO₄ immobilization were selected as adsorbent to remove Hg²⁺ from water phase. The optimum conditions of adsorption test of ionic liquid immobilized by multi-walled carbon nanotubes were as follows: the initial concentration of Hg²⁺ was 400 mg/L, the adsorbent addition amount was 40 mg, the temperature was 20 °C, the reaction time was 200 min, the removal rate of Hg²⁺ peaked at 62.95%, the adsorption capacity was reached 79.00 mg/g. The optimum conditions of adsorption test of ionic liquid immobilized by activated carbon were as follows: the initial concentration of Hg²⁺ was 300 mg/L, the adsorbent addition amount was 0.2 g, the temperature was 20 °C, pH was 2.0, the reaction time was 100 min, the removal rate of Hg²⁺ was more than 99%, the adsorption capacity was 118.65 mg/g. The adsorption isotherm fitting study found that the adsorption of adsorbent on Hg²⁺ was more in line with the Langmuir model, and the adsorption kinetics study shows that the adsorption process is consistent with the pseudo-second-order kinetic equation. The results of kinetic analysis are further verified by thermodynamic analysis.

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