Temporal and spatial trends in sediment contaminants associated with toxicity in California watersheds

Siegler, Katie; Phillips, Bryn M.; Anderson, Brian S.; Voorhees, Jennifer P.; Tjeerdema, Ron S.

Temporal and spatial trends in sediment contaminants associated with toxicity in California watersheds

2015

Siegler, Katie | Phillips, Bryn M. | Anderson, Brian S. | Voorhees, Jennifer P. | Tjeerdema, Ron S.

California's Stream Pollution Trends program (SPoT) assesses long-term water quality trends, using 100 base-of-the-watershed sampling sites. Annual statewide sediment surveys from 2008 to 2012 identified consistent levels of statewide toxicity (19%), using the freshwater amphipod Hyalella azteca. Significant contaminant trends included a decrease in PCBs, stable concentrations of metals and PAHs, and a statewide increase in detections and concentrations of pyrethroid pesticides. The pyrethroid pesticide bifenthrin was detected in 69% of samples (n = 410). Detection of toxicity increased in a subset of samples tested at a more environmentally relevant test temperature (15 °C), and the magnitude of toxicity was much greater, indicating pyrethroid pesticides as a probable cause. Pyrethroid toxicity thresholds (LC50) were exceeded in 83% of samples with high toxicity. Principal components analysis related pyrethroids, metals and total organic carbon to urban land use.

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