Flower-like molybdenum disulfide decorated ZIF-8-derived nitrogen-doped dodecahedral carbon for electro-catalytic degradation of phenol
2022
Fan, Lei | Gong, Yuguo | Wan, Jiafeng | Wei, Yuhan | Shi, Haolin | Liu, Chuntao
In this work, flower-like molybdenum disulfide was constructed on the surface of ZIF-8-derived nitrogen-doped dodecahedral carbon (ZNC) for the electrocatalytic degradation of phenol. The flower-like nanostructure of MoS₂@ZNC contributed to the exposure of more edge-active sites of MoS₂. At the same time, Mo⁴⁺ and Mo⁶⁺ co-existed in MoS₂@ZNC, which promoted the generation of H₂O₂ and •OH, and improved the catalytic activity of composite materials. In addition, electrochemical performance analysis showed that MoS₂ loaded on the surface of ZNC significantly improved the redox capacity of the material, and the composite ratio of MoS₂ and ZNC affected the structure and properties of MoS₂@ZNC composites. Moreover, the electrochemical performance of prepared MoS₂@ZNC was evaluated by the generation of hydroxyl (•OH) and the degradation efficiency of phenol. The results showed that MoS₂@ZNC-2 had an excellent phenol degradation efficiency (98.8%) and COD removal efficiency (86.8%) within 120 min. Furthermore, MoS₂@ZNC cathode still maintained good performance after being experimented with 20 times, indicated the excellent stability of MoS₂@ZNC.
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