Dihydropyridazine-appended dibenzosuberenones as a new class of fluorophores: Application to fluoride sensing
2017
Koçak, Ramazan | Yıldız, Dilan | Bozkaya, Uğur | Daştan, Arif | Bozdemir, Özgür Altan
Highly fluorescent, novel dihydropyridazine-appended dibenzosuberenone type dye molecules were obtained in a single step from simple compounds using Diels-Alder chemistry. This new fluorophore structure can be used for the construction of fluorescent chemosensors, as exemplified by selective and sensitive fluoride ion sensing. The –N–H protons in these structures are acidic enough to allow for fluoride-induced deprotonation, leading to a significant color change as well as a concomitant fluorescence quenching. These fluorophores possess large Stokes shifts, high quantum yields, and long fluorescence lifetimes; therefore, this study potentially paves the way for the construction of novel dye molecules for use in fluorescent dye applications.
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