Development of a solvent selection guide for aldehyde-based direct reductive amination processes
2013
McGonagle, Fiona I. | MacMillan, Donna S. | Murray, Jane | Sneddon, Helen F. | Jamieson, Craig | Watson, Allan J. B.
A range of alternative, more environmentally conservative solvents have been evaluated for use within the direct reductive amination reactions of aldehydes using borane-based reductants. The data generated has been used to develop a guide to facilitate replacement of less desirable chlorinated solvents, such as DCE, from these widely used synthetic processes.
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