Electromagnetic Mill Promoted Mechanochemical Solvent-Free Palladium-Catalyzed Borylation of Aryl Bromides
2022
Liu, Yunxia | Li, Xin | Liu, Qing | Li, Xinjin | Liu, Hui
The electromagnetic mill (EMM) promoted mechanochemical solvent-free palladium-catalyzed borylation of aryl bromides using low palladium catalyst loading (0.05–0.5 mol %) was realized. This protocol exhibits many advantages, such as broad substrate scope, good functional group tolerance, short reaction times, no additional heating, and practical gram-scale synthesis. This EMM system not only showed excellent prospects for industrial application but also unlocked broad areas of solvent-free solid-state metal-catalyzed syntheses.
اظهر المزيد [+] اقل [-]الكلمات المفتاحية الخاصة بالمكنز الزراعي (أجروفوك)
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