(La0.8Sr0.2)MnO3-Ni composite for the interconnect of solid oxide cells: effect of starting Ni particle size on sintering and electrical properties
2021
Qin, Fen | Wang, Anqi | Park, Jong-Sung | Kim, Sun-dong | Woo, Sang Kook | Lee, Jung-Kun
This study demonstrates the feasibility of applying La₀.₈Sr₀.₂MnO₃ (LSM)-Ni oxide-metal composite to an interconnect layer for anode-supported solid oxide cells (SOCs) operated at 700 °C. The sintering behavior of LSM-Ni composites and the electrical properties of LSM-Ni composite in both reducing and oxidizing atmospheres were systematically examined. The densification and final microstructure of LSM-Ni composites are tailored by varying the size and content of Ni particles. A part of smaller Ni particles reacts with LSM matrix and forms a second phase, Sr-doped La₂NiO₄. The addition of Sr to La₂NiO₄ decreases the melting temperature of La₂NiO₄, which causes the liquid phase sintering and increases the density of the sintered of LSM-Ni composites. It is also found that LSM-Ni composites are electrically conductive, regardless of the atmosphere. In oxidizing atmospheres, LSM perovskite serves as the major conductive matrix. In reducing atmospheres, on the other hand, embedded Ni forms metallic percolation path and compensates for the decrease in the electrical conductivity of reduced LSM ceramics. This LSM-Ni is used to coat the multilayer thick film of LSM-Ni and LSM. The multilayer film exhibits higher and more stable electric conductivity than the single layer thick film of LSM in a simulated SOC operation environment. This shows that LSM-Ni composite can be a useful component of the interconnect of SOC, which maintains the good electric conductivity in both air and H₂.
اظهر المزيد [+] اقل [-]الكلمات المفتاحية الخاصة بالمكنز الزراعي (أجروفوك)
المعلومات البيبليوغرافية
تم تزويد هذا السجل من قبل National Agricultural Library