Graphene Oxide Monolayer as a Compatibilizer at the Polymer–Polymer Interface for Stabilizing Polymer Bilayer Films against Dewetting

Kim, Tae-Ho; Kim, Hyeri; Choi, Ki-In; Yoo, Jeseung; Seo, Young-Soo; Lee, Jeong-Soo; Koo, Jaseung

Graphene Oxide Monolayer as a Compatibilizer at the Polymer–Polymer Interface for Stabilizing Polymer Bilayer Films against Dewetting

2016

We investigate the effect of adding graphene oxide (GO) sheets at the polymer–polymer interface on the dewetting dynamics and compatibility of immiscible polymer bilayer films. GO monolayers are deposited at the poly(methyl methacrylate) (PMMA)–polystyrene (PS) interface by the Langmuir–Schaefer technique. GO monolayers are found to significantly inhibit the dewetting behavior of both PMMA films (on PS substrates) and PS films (on PMMA substrates). This can be interpreted in terms of an interfacial interaction between the GO sheets and these polymers, which is evidenced by the reduced contact angle of the dewet droplets. The favorable interaction of GO with both PS and PMMA facilitates compatibilization of the immiscible polymer bilayer films, thereby stabilizing their bilayer films against dewetting. This compatibilization effect is verified by neutron reflectivity measurements, which reveal that the addition of GO monolayers broadens the interface between PS and the deuterated PMMA films by 2.2 times over that of the bilayer in the absence of GO.

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