Macropolyhedral boron-containing cluster chemistry. Synchrotron X-ray structural analysis of [(PMe₂Ph)₂Pd₂B₁₆H₂₀(PMe₂Ph)₂] and [(PMe₂Ph)₃Pt₂B₁₆H₁₈(PMe₂Ph)]: models of intermediates to more condensed metallaboranes from the [(PMe₂Ph)₂PtB₈H₁₂] thermolysis system
2005
Londesborough, Michael G. S. | MacLean, Elizabeth J. | Teat, Simon J. | Thornton-Pett, Mark | Kennedy, John D.
Thermolyses of [(PMe₂Ph)₂PdB₈H₁₂] and [(PMe₂Ph)₂PtB₈H₁₂] respectively yield eighteen-vertex [(PMe₂Ph)₂Pd₂B₁₆H₂₀(PMe₂Ph)₂] and [(PMe₂Ph)₃Pt₂B₁₆H₁₈(PMe₂Ph)], which exhibit structure models for probable successive precursive intermediates for the more condensed macropolyhedral metallaboranes [(PMe₂Ph)₄Pt₃B₁₄H₁₆], [(PMe₂Ph)₂Pt₂B₁₂H₁₆] and [(PMe₂Ph)₂Pt₂B₁₆H₁₅(C₆H₄Me)(PMe₂Ph)] that have previously been reported as products from [(PMe₂Ph)₂PdB₈H₁₂] thermolyses.
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