Dynamic separation of ultradilute CO₂ with a nanoporous amine-based sorbent
2012
He, Leilei | Fan, Maohong | Dutcher, Bryce | Cui, Sheng | Shen, Xiao-dong | Kong, Yong | Russell, Armistead G. | McCurdy, Patrick
An alternative amine-based sorbent (RFAS) was developed in this work. RFAS was assessed under various conditions. Studies show that the CO₂ sorption capacities of RFAS increase considerably with N loading, slowly with increasing temperature (apparently contrary to the prediction with the isothermal equation of exothermic sorption), and gradually with the decease of gas flow rate in the tested range. In addition, CO₂ sorption capacity increases and then decreases as the H₂O:CO₂ mole ratio increases, and the stoichiometric ratio 1:1 is the turning point. The CO₂ sorption capacities achieved by RFAS with 8.07mmolN/g for air with 400ppm CO₂ and the CO₂–N₂ gas mixtures containing 1 vol% CO₂ are 1.78mmol CO₂/g and 1.92mmol CO₂/g, respectively, higher than those reported in the most recent literature. A kinetic model corresponding to three proposed pathways is derived and expected to quantitatively predict the CO₂ sorption characteristics given that the involved parameters can be established in the future. The half-CO₂-adsorption and desorption times of RFAS along with temperatures are used to evaluate the dynamics of the sorbent. The adsorbed CO₂ can be completely desorbed at only 80°C within as short as 30min. Low temperature desorption not only leads to the decrease in energy consumption but also benefits the structure stability of RFAS. The CO₂ sorption capacities of RFAS within 10 sorption–desorption cycles are repeatable. All the results confirm that RFAS is a highly adsorptive, reversibly dynamic, and regenerable sorbent for capture of ultradilute CO₂ from gas mixtures.
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