The structural determination of endohedral metallofullerene Gd@C₈₂ by XANES
2008
Liu, Lei | Gao, Bin | Chu, Wangsheng | Chen, Dongliang | Hu, Tiandou | Wang, Chunru | Dunsch, Lothar | Marcelli, A. | Luo, Yi | Wu, Ziyu
Although the Gd ion in Gd@C₈₂ has been shown to lie above the C–C bond on the C₂ axis as an anomalous structure from the MEM/Rietveld analysis, the present XANES study reveals that it lies above the hexagon on the C₂ axis as a normal structure, and Gd oscillates around its equilibrium position with an amplitude increasing with temperature increase.
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