Homochirality in space – Selective enrichment of chiral molecules on chiral surfaces
2014
Marloie G. | Pauzat F. | Ellinger Y. | Markovits A. | Pilmé J.
Life on Earth, as we know it to day, is inseparable from homochirality. The presence of an enantiomeric excess in carbonaceous chondrites is well documented; among the different hypotheses considered to explain this undisputed fact, we chose to investigate the possibilities open by a selective adsorption on a chiral surface that would engage a process of enantiomeric enrichment. The chiral surface is that of the α-quartz { 10 10¯ } $\left\{ {10\,\overline {10} } \right\}$ and the chiral molécule is lactic acid, HOCH(CH3)COOH. In this theoretical work we rely on numerical simulations based on Density Functional Theory (DFT) that proved efficient in the super-molecule and periodic approaches to this category of phenomena. In view of the different types of adsorption sites, a statistical treatment was necessary; it shows that (S)-lactic acid is preferentially adsorbed with a selectivity of ~0.7 kcal/mol with respect to the (R) isomer.
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