Origin and Salinization Processes of Groundwater in the Semi-Arid Area of Zagora Graben, Southeast Morocco

Located in the southeastern region of Morocco, the Zagora area mainly relies on groundwater as a source of water supply. However, this groundwater is often of concern, due to the limited recharge and unfavorable geological conditions for the development of the aquifer. Despite this, private wells in the Zagora ditch reveal relatively rich water resources. Geochemical and isotopic studies were conducted in the area to understand the origin of the groundwater and its salinity, aiding in informed water management strategies to assist in better planning and regulation of well construction, as well as in mitigating the impacts of high salinity on local water supply and agricultural systems. The results show that the water quality varies, with some wells having conductivity values in excess of 5 mS/cm. Most groundwater samples have high salinity and low pH due to the CO₂ dissolved in groundwater. Geochemical analysis indicated two chemical facies: chloride–sulfate calcic/magnesic and bicarbonate calcic/magnesic. The presence of Na⁺ and Cl⁻ indicated that the origin of these two elements in these waters was the dissolution of halite, with some samples showing an enrichment of Na⁺ compared to Cl⁻. This could be attributed to cation exchange. The concentration of Ca²⁺ and HCO₃⁻ suggested that their origin is the dissolution of calcite and the weathering of calcium silicate minerals such as plagioclase. The isotopic analysis showed that the δ¹⁸O values ranged from −10.98‰ to −8.54‰, and δ²H values ranged from −75.9‰ to −62.3‰. This indicated that the groundwater originated from the High Atlas with a recharge altitude between 2600 m and 2800 m. The groundwater flows into the graben through fissures and regional fault networks.