PM₂.₅ is one of the most studied atmospheric pollutants due to its adverse impacts on human health and welfare and the environment. An improved model (the chemical mass balance gas constraint-Iteration: CMBGC-Iteration) is proposed and applied to identify source categories and estimate source contributions of PM₂.₅. The CMBGC-Iteration model uses the ratio of gases to PM as constraints and considers the uncertainties of source profiles and receptor datasets, which is crucial information for source apportionment. To apply this model, samples of PM₂.₅ were collected at Tianjin, a megacity in northern China. The ambient PM₂.₅ dataset, source information, and gas-to-particle ratios (such as SO₂/PM₂.₅, CO/PM₂.₅, and NOx/PM₂.₅ ratios) were introduced into the CMBGC-Iteration to identify the potential sources and their contributions. Six source categories were identified by this model and the order based on their contributions to PM₂.₅ was as follows: secondary sources (30%), crustal dust (25%), vehicle exhaust (16%), coal combustion (13%), SOC (7.6%), and cement dust (0.40%). In addition, the same dataset was also calculated by other receptor models (CMB, CMB-Iteration, CMB-GC, PMF, WALSPMF, and NCAPCA), and the results obtained were compared. Ensemble-average source impacts were calculated based on the seven source apportionment results: contributions of secondary sources (28%), crustal dust (20%), coal combustion (18%), vehicle exhaust (17%), SOC (11%), and cement dust (1.3%). The similar results of CMBGC-Iteration and ensemble method indicated that CMBGC-Iteration can produce relatively appropriate results.

Precipitation samples were collected at five rural and one urban sites in the Three Gorges Reservoir Region (TGR), China from March 2014 to February 2016. The inorganic reactive nitrogen (Nr) contents were analysed to investigate their wet deposition flux, budget, and sources in the area. Annual Nr wet deposition varied from 7.1 to 23.4 kg N ha⁻¹ yr⁻¹ over the six sites during the two-year study campaign. The six-site average Nr wet deposition flux was 17.1 and 11.7 kg N ha⁻¹ yr⁻¹ in 2014 and 2015, respectively, with 71% from NH₄⁺ and 29% from NO₃⁻. Dry deposition flux was estimated using the inferential method, which combined the measured ambient concentrations and modelled dry deposition velocities. The total (dry + wet) Nr deposition fluxes were estimated to be 21.4 kg N ha⁻¹ yr⁻¹ in 2014 and 16.0 kg N ha⁻¹ yr⁻¹ in 2015 at rural sites, and 31.4 and 25.3 kg N ha⁻¹ yr⁻¹ at the urban site. Annual average volume weighted mean (VWM) concentrations in precipitation at all the six sites differed little for NO₃⁻ but up to a factor of 2.0 for NH₄⁺ with the highest value at the urban site. Industrial emissions, agricultural emissions, soil dust, and biomass burning were identified as potential sources of the major inorganic ions in precipitation using factor analysis and correlation analysis. Conditional probability function (CPF) analysis indicated that the urban site was predominantly affected by industrial emissions from a power plant, cement manufactory, and salt chemical facility located ∼13 km southeast of the sampling site.

The aim of this study was to assess, for the first time, the concentrations, sources, dry deposition and human health risks of polycyclic aromatic hydrocarbons (PAHs), aliphatic hydrocarbons (AHs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in total suspended particle (TSP) samples collected in Bizerte city, Tunisia (North Africa), during one year (March 2015–January 2016). Concentrations of PAHs, AHs, PCBs and OCPs ranged 0.5–17.8 ng m−3, 6.7–126.5 ng m−3, 0.3–11 pg m−3 and 0.2–3.6 pg m−3, respectively, with higher levels of all contaminants measured in winter. A combined analysis revealed AHs originating from both biogenic and petrogenic sources, while diesel vehicle emissions were identified as dominant sources for PAHs. PCB potential sources included electronic, iron, cement, lubricant factories located within or outside Bizerte city. The dominant OCP congeners were p,p′-DDT and p,p′-DDE, reflecting a current or past use in agriculture. Health risk assessment showed that the lifetime excess cancer risk from exposure to airborne BaP was negligible in Bizerte, except in winter, where a potential risk to the local population may occur.

Source samples including crustal dust, cement dust, coal combustion were sampled and ambient samples of PM₂.₅ and PM₁₀ were synchronously collected in Hefei from April to December 2014. The size distributions of the markers in the measured source profiles were incorporated into ME-2 solution to develop a new method, called the SDABB model (an advanced ABB three-way factor analysis model incorporating size distribution information). The performance of this model was investigated using three-way synthetic and ambient dataset. For the synthetic tests, the size distributions of markers estimated by the SDABB model were more consistent with true condition. The AAEs between estimated and observed contributions of the SDABB ranged from 15.2% to 29.0% for PM₁₀ and 19.9%–31.6% for PM₂.₅, which is lower than those of PMF2. For the ambient PM, six source categories were identified by SDABB for both sizes, although the profiles were different. The source contributions were sulphate (33.33% and 24.53%), nitrate and SOC (22.33% and 18.16%), coal combustion (19.01% and 18.23%), vehicular exhaust (12.99% and 12.07%), crustal dust (10.69% and 19.40%) and cement dust (1.65% and 5.39%) for PM₂.₅ and PM₁₀ respectively. In addition, the estimated ratios of Al, Si, Ti and Fe in CRD were 0.76, 0.84, 1.10 and 0.85; those of Al and Si in CC were 0.42 and 0.66; Ca and Si in CD were 0.95 and 1.10; NO₃⁻ and NH₄⁺ in nitrate were 1.11 and 1.01; and SO₄²⁻ and NH₄⁺ in sulphate were 0.96 and 1.16. These modeled ratios were consistent with the measured ratios. The size distribution of contributions also came close to reality. Thus, the advanced SDABB three-way model can better capture the characteristics of sources between sizes by effectively incorporating the size distributions of the markers as physical constraints.

The production of polychlorinated biphenyls (PCBs) has been banned globally for decades, but PCB concentrations in environmental media remain relatively high, especially in urban areas. Emissions estimates, studies of soil gradients between urban and rural areas, and quantitative identification of regional sources of PCBs in soils are necessary for understanding the environmental behavior of PCBs. In this study, regional PCB emissions were estimated at a resolution of 10 km × 10 km, and the spatial distribution of soil PCBs from urban to rural areas was studied along the Bohai and Yellow Sea regions. Compared with rural areas, mean PCB concentrations in urban soils (20.7 ng/g) were found to be higher, and concentrations decreased with distance from the city. Across both latitude and longitude directions, high PCB emissions in urban areas matched the distribution of total PCB concentrations in soils. The concentrations of the pollutants PCB28, PCB52, PCB101, PCB118, PCB138, PCB153, and PCB180 in soils originated from 5-year emissions, and accounted for 97%, 95%, 84%, 81%, 58%, 57%, and 27% of the total emissions, respectively. Unintentionally produced PCB (UP-PCB) emissions, which are mainly derived from cement (42%), pig iron (37%), crude steel (18%), and rolled steel (3%) industries, are the major contributors to PCBs in soils. Further identification of the sources and fates of PCBs requires a combination of field, laboratory, and modeling efforts.

To assess the spatial distribution and ecological risk assessment along the Red Sea coast, Saudi Arabia, 30 samples were collected for aluminum, chromium, copper, zinc, cadmium, lead, mercury, iron, cobalt, nickel and organic matter analysis. The descending order of metal concentrations was Al > Fe > Cr > Cu > Zn > Ni > Co > Pb > Hg > Cd. Average values of enrichment factor of Hg, Cd, Cu, Co, Cr, Ni, Pb and Zn were higher than 2 (209.50, 25.52, 20.36, 9.62, 7.28, 6.52, 6.21 and 6.07 respectively), which means anthropogenic sources of these metals. The average levels most of the studied metals were lower than those of the background shale and the earth crust and those recorded along most worldwide coasts, while the average values of zinc, copper, cobalt and nickel were higher than the values recorded from the Red Sea coast, the Gulf of Aqaba and some Caspian Sea coasts. The Duba bulk plant-Saudi Aramco, Duba refinery station and the tourist resort were the possible anthropogenic sources of pollutants in the southern part of the study area; and the landfilling, cement factory and Duba port and shipment operations in the central part, while the landfilling resulting from construction of the green Duba power plant and crowded fish boats were the possible sources in the northern part.

Photosynthetic microalgal growth is a promising tool for mitigation of gaseous effluent from the cement production, which is highly implicated in global warming and climate change. We investigated the effects of actual cement industry flue gas on the physiology of Chlorella vulgaris under laboratory-controlled conditions. We evaluated the growth, photosynthetic performance, intracellular metal content, total proteins, and carbohydrates of C. vulgaris under three gas input rates: 9, 36, and 54 L d⁻¹; compressed air (54 L d⁻¹) was used as control. The results showed no correlation between the flue gas input rates on total proteins and carbohydrates in the algal biomass, and no effects on growth rates. However, rapid light curves indicated that the light use efficiency (α) and the maximum relative electron transport rate (rETRₘₐₓ) were stimulated when applying 9 and 36 L d⁻¹. Metal analysis revealed an accumulation of Cr, Zn, and Ni in the algal biomass exposed to flue gas (54 L d⁻¹) compared to the control. Thermogravimetry and differential thermal analysis showed that 70% of the cement kiln dust were composed by uncalcined limestone, which may have stimulated photosynthesis, as indicated by the rapid light curve parameters. In general, C. vulgaris can be considered a robust organism for cement flue gas bioremediation.

The Cerrejón mine has identified fires in its coal production seams for a few years in its operation. Fires are produced as a result of spontaneous combustion phenomena. Coal spontaneous combustion is a phenomenon that occurs naturally during coal oxidation when exposed to atmospheric conditions, due to erosion processes, geological and mining practices. This phenomenon is a subject of great concern in the world’s coal mines, as it causes environmental problems, generating emissions of polluting gases into the atmosphere and economic losses due to reserve consumption. In this work, we seek to optimize the prevention and extinction processes used by the company. In terms of prevention, the current state was evaluated and alternatives, such as diluted bitumen and brine (combustion inhibitor), cement/slaked lime, fine sand cement, and clinker/slaked lime were developed to avoid ignition. As far as extinction is concerned, an additional methodology for medium magnitude fires was determined, in order to improve extinction times through the use of cooling. It was determined that the bitumen/brine has better adhesion and durability properties in the coal seam. Extinction through reagent cooling is quicker, thus improving the backhoe’s productivity and minimizing costs.

Cement solidification is an important pre-treatment technology for municipal solid waste incineration (MSWI) fly ash into landfill. The physicochemical properties and leaching characteristics are the foundation for assessing the long-term stability of the fly ash solidified with benchmark cement in landfills. The leaching performances of bulk components (Na, K, Ca, Cl, CO₃²⁻, and SO₄²⁻) and heavy metals (Cu, Zn, Cr, Pb, and Zn) were analyzed based on the percolation column test and pH dependent test respectively. The research showed that in the cement-solidified fly ash, Na and K were mainly in the form of soluble chloride salts and would be washed out severely at the initial leaching stage due to the weak fixation effect of cement. Moreover, a considerable amount of Ca was washed out simultaneously with Na and K, causing a temporary increase in pH value, and then Ca leaching was controlled by the solubility of minerals, mainly calcium carbonate, ettringite formed with CO₃²⁻ and SO₄²⁻. Cement solidification reduced the cumulative release of mobile Cu, Zn, Cr, Pb, and Cd contained in MSWI fly ash. In the cement-solidified fly ash, the leaching of Cu and Zn was controlled by mineral solubility under alkaline conditions, Cr was dependent on the redox conditions, and Pb was related to the complex structures formed with Si–O bonds of silicates. A further research on the long-term stability of the cement-solidified fly ash in landfills was needed.

In this study, a novel method for the treatment of polycyclic aromatic hydrocarbon -contaminated soil using cement-activated persulfate was developed. The removal of PAHs in soil rose with increasing initial persulfate concentration, initial Portland cement (PC) concentration, and oxidation reaction time. At an initial persulfate and PC concentration of 19.20 mmol/kg and 10% of soil weight and a reaction time of 2 h, the removal rate of PAHs reached 57.3%. Residual PAHs were mainly adsorbed within the soil granules and thus became less available. The mechanism of PC facilitating the oxidation reaction was that PC addition can increase the pH and temperature of the system. When the soil was stabilized/solidified by 10% of PC, the leaching concentration of PAHs and TOC was significantly higher than that leached from untreated soil. Persulfate oxidation decreased the leaching concentration of PAHs but increased the leaching concentration of TOC in solidification/stabilization products. The addition of activated carbon can decrease the leaching concentrations of both PAHs and TOC. Freeze-thaw durability tests revealed that the leachability of PAHs was not affected by freeze-thaw cycles. The unconfined compressive strength (UCS) of treated soil samples after 12 freeze-thaw cycles was only 49.0% of that curing for 52 days, but the UCS was still > 1 MPa. The treated soil samples can resist disintegration during the process of freeze-thaw cycles.