In this paper the results of determination of natural waters from the territory of the township Smederevska Palanka and Rekovac (Serbia, Yugoslavia) are presented. The content of metals in waters was determined by the AAS method and other parameters were determined by spectrophotometric and potentiometric method.

The reaction of Pd(II) with 1,8-dihydroxy-2-(pyrazol-5-ylazo)-naphthalen-3,6-disulphonic acid immobilized by physical sorption onto Dowex 1-X8 ion-exchange resin was investigated with the aim to develop the sorption-spectroscopic test method for the detection of low Pd(II) concentrations in water. The resin phase absorption spectra of the reagent and its Pd(II) complex were followed. The immobilized reagent has the spectral characteristics similar to those in the water and forms with Pd(II) 1:1 complex with the absorption maximum at 650 nm. Parameters, such as pH, wavelength and contact time have been optimized for a given amount of the sorbed reagent. The experimental conditions for the linear dependence of absorbance vs. Pd(II) concentration have been determined.

In this investigation the applied method for lead determination in traces, from 10E-6 - 10E-10 mol/cubic dm, was Potentiometric Stripping Analysis (PSA). The main attribute of this method is possibility to detect very low metal concentrations. The investigation results of level concentration of lead into the top, natural and atmospheric water from some towns of Serbia (Yugoslavia), including city of Belgrade, are given. The investigation was carried out in some towns of Serbia (Yugoslavia), including city of Belgrade, during the 1994-1995.

The groundwater quality on the National Park Kopaonik is determined by the chemical and radioactive structure of water, formed through the processes that due to the contact of minerals from the water - bearing rocks and groundwater. Atmosphere precipitation are the main source of the entire resources of the ground water in the national park, and the aggressive components that are carried into the underground are the main catalyst in the process of leaching of the predominant minerals from the water-bearing rocks. In the national park, crystalline and marble limestones have the greatest water potential in the sense of the quantity and quality, and the granite massif dispose with the ground water, with the most complex radioactive structure.

In the course of implementation of project Ecological Significance Evaluation of River Moravica Basin with Pollutants Identification, supported by REC and DRP, chemical and physical water analysis were done, as well as slime analysis. Heavy metals presence in water, herb Mentha aquatica and slime was analysed at six relevant locations downstream river Moravica. Heavy metals test results in slime and herb Mentha aquatica points out the presence of Zn, Cu, Fe, Mn, with heavy metals concentration rise from spring to mouth of river Moravica to river Juzna Morava. Chemical and physical analysis of water content, and detection of heavy metals presence in herb Mentha aquatica - as bioindicator and in slime, shows on water contamination with heavy metals as the inflow result of waste waters from numerous polluters.

During the 2004 research of Moraca river water quality was conducted onto six localities: Pernica, Zlatica, Gradska plaza, Kolektor, Grbavci and Vukovci. Physical, chemical and microbiological properties were analyzed. Physical and chemical analyses done were: water temperature, air temperature, pH, electro-conductivity, KMnO4 consumption, dissolved O2 and BCO5 (biological consumption of oxygen in five days). Microbiological analysis included determination of the total number of aerobic mezophyll bacteria, oligotrophic and heterotrophic bacteria, as well as the most probable number of colliform bacteria. In addition to distribution and population dynamics, identification of the bacteria was also done. Microbiological water analysis were performed using standard bacteriologic methods and identification of the bacteria using INVIC or, when needed, using API diagnostics.