Disinfection means the killing of pathogenic organisms (e.g. bacteria and its spores, viruses, protozoa and their cysts, worms, and larvae) present in water to make it potable for other domestic works. The substances used in the disinfection of water are known as disinfectants. At municipal level, chlorine (Cl₂), chloramines (NH₂Cl, NHCl₂), chlorine dioxide (ClO₂), ozone (O₃) and ultraviolet (UV) radiations, are the most commonly used disinfectants. Chlorination, because of its removal efficiency and cost effectiveness, has been widely used as method of disinfection of water. But, disinfection process may add several kinds of disinfection by-products (DBPs) (∼600–700 in numbers) in the treated water such as Trihalomethanes (THM), Haloacetic acids (HAA) etc. which are detrimental to the human beings in terms of cytotoxicity, mutagenicity, teratogenicity and carcinogenicity. In water, THMs and HAAs were observed in the range from 0.138 to 458 μg/L and 0.16–136 μg/L, respectively. Thus, several regulations have been specified by world authorities like WHO, USEPA and Bureau of Indian Standard to protect human health. Some techniques have also been developed to remove the DBPs as well as their precursors from the water. The popular techniques of DBPs removals are adsorption, advance oxidation process, coagulation, membrane based filtration, combined approaches etc. The efficiency of adsorption technique was found up to 90% for DBP removal from the water.

Manganese oxides (MnOₓ) and Mn²⁺ usually co-exist in the natural environment, as well as in water treatments for Mn²⁺ removal. Therefore, it is necessary to investigate the influence of Mn²⁺ on the stability of MnOₓ nanoparticles, as it is vital to their fate and reactivity. In this study, we used the time-resolved dynamic light scattering technique to study the influence of Mn²⁺ on the initial aggregation kinetics of MnOₓ nanoparticles. The results show that Mn²⁺ was highly efficient in destabilizing MnOₓ nanoparticles. The critical coagulation concentration ratio of Mn²⁺ (0.3 mM) to Na⁺ (30 mM) was 2⁻⁶.⁶⁴, which is beyond the ratio range indicated by the Schulze-Hardy rule. This is due to the coordination bond formed between Mn²⁺ and the surface O of MnOₓ, which could efficiently decrease the negative surface charge of MnOₓ. As a result, in the co-presence of Mn²⁺ and Na⁺, a small amount of Mn²⁺ (5 μM) could efficiently neutralize the negative charge of MnOₓ, thereby decreasing the amount of Na⁺, which mainly destabilized nanoparticles through electric double-layer compression, required to initiate aggregation. Further, Mn²⁺ behaved as a cation bridge linking both the negatively charged MnOₓ and humic acid, thereby increasing the stability of the MnOₓ nanoparticles as a result of the steric repulsion of the adsorbed humic acid. The results of this study enhance the understanding of the stability of the MnOₓ nanoparticles in the natural environment, as well as in water treatments.

Ambient ultrafine particles (UFPs: particles of diameter less than 100 nm) cause significant adverse health effects. As people spend most time indoors, the outdoor-to-indoor transport of UFPs plays a critical role in the accuracy of personal exposure assessments. Herein, a strategy was proposed to measure and analyze the infiltration factor (Fᵢₙf) of UFPs, an important parameter quantifying the fraction of ambient air pollutants that travel inside and remain suspended indoors. Ninety-three measurements were conducted in 11 residential rooms in all seasons in Beijing, China, to investigate Fᵢₙf of UFPs and its associated influencing factors. A multilevel regression model incorporating eight possible factors that influence infiltration was developed to predict Fᵢₙf and FᵢₙfSOA (defined as the ratio of indoor to outdoor UFP concentrations without indoor sources, but with indoor secondary organic aerosol (SOA) formation). It was found that the air change rate was the most important factor and coagulation was considerable, while the influence of SOA formation was much smaller than that of other factors. Our regression model accurately predicted daily-average Fᵢₙf. The annually-averaged Fᵢₙf of UFPs was 0.66 ± 0.10, which is higher than that of PM₂.₅ and PM₁₀, demonstrating the importance of controlling indoor UFPs of outdoor origin.

Inflammation and the coagulation cascade are considered to be the potential mechanisms of ambient particulate matter (PM) exposure-induced adverse cardiovascular events. Tumor necrosis factor-alpha (TNF-α), interleukin-6 (IL-6), interleukin-8 (IL-8), and fibrinogen are arguably the four most commonly assayed markers to reflect the relationships of PM with inflammation and blood coagulation. This review summarized and quantitatively analyzed the existing studies reporting short- and long-term associations of PM₂.₅(PM with an aerodynamic diameter ≤2.5 μm)/PM₁₀ (PM with an aerodynamic diameter≤10 μm) with important inflammation and blood coagulation markers (TNF-α, IL-6, IL-8, fibrinogen). We reviewed relevant studies published up to July 2020, using three English databases (PubMed, Web of Science, Embase) and two Chinese databases (Wang-Fang, China National Knowledge Infrastructure). The OHAT tool, with some modification, was applied to evaluate risk of bias. Meta-analyses were conducted with random-effects models for calculating the pooled estimate of markers. To assess the potential effect modifiers and the source of heterogeneity, we conducted subgroup analyses and meta-regression analyses where appropriate. The assessment and correction of publication bias were based on Begg’s and Egger’s test and “trim-and-fill” analysis. We identified 44 eligible studies. For short-term PM exposure, the percent change of a 10 μg/m³ PM₂.₅ increase on TNF-α and fibrinogen was 3.51% (95% confidence interval (CI): 1.21%, 5.81%) and 0.54% (95% confidence interval (CI): 0.21%, 0.86%) respectively. We also found a significant short-term association between PM₁₀ and fibrinogen (percent change = 0.17%, 95% CI: 0.04%, 0.29%). Overall analysis showed that long-term associations of fibrinogen with PM₂.₅ and PM₁₀ were not significant. Subgroup analysis showed that long-term associations of fibrinogen with PM₂.₅ and PM₁₀ were significant only found in studies conducted in Asia. Our findings support significant short-term associations of PM with TNF-α and fibrinogen. Future epidemiological studies should address the role long-term PM exposure plays in inflammation and blood coagulation markers level change.

Chemical conditioning is an effective strategy for improved river sediment dewatering affecting both the dewatering efficiency and subsequent resource utilization of the dewatered cake. Two types of conditioning agents, polyaluminium chloride (PAC)/cationic polyacrylamide (PAM) (coagulation precipitation conditioning agent, referred to as P–P conditioning) and ferrous activated sodium persulfate (advanced oxidation conditioning agent, referred to as F–S conditioning) were examined. With increasing leach liquid to solid (L/S) ratio the concentration of Cd for the real time leachates from the dewatered cakes decreased, but the leaching ratio of Cd in both P–P and F–S dewatered cakes increased. With the same L/S, the leaching ratio was reduced for both types of conditioning, as compared to no conditioning, with the leaching ratio being least with F–S conditioning. The leaching ratio of Cd in the dewatered cake with L/S of 100 L kg⁻¹ was reduced from 21.3% of the total Cd present for the un-conditioned sediment to 12.5% upon P–P conditioning and 11.6% upon F–S conditioning. Furthermore, the different conditioning methods affected the Cd speciation in the dewatered cakes reducing the easy-to-leach speciation of exchangeable and carbonate-bound Cd species and increasing the potential-to-leach speciation of iron-manganese oxide and organically bound Cd species and also the difficult-to-leach species. Risk assessment indicates that the risk due to Cd leaching from the dewatered cakes at L/S of 100 L kg⁻¹ was reduced from high risk to medium risk after P–P and F–S conditioning with reduced bioavailability.

Environmental colloids play crucial roles in the transport of environmental pollutants in porous media by acting as pollutant carriers. In this work, the dispersion stability and correlated transport of kaolinite colloid were investigated as a function of solution pH, solution ionic strength, and concentration of humic acid (HA), the roles of kaolinite colloid in driving Eu(III) transport were discussed. The results showed that the dispersion of kaolinite colloid was favorable at alkaline and extremely acidic pH values, the trend of aggregation with varying pH was critically reversed at pH ∼3.2 due to the transformation of surface electrical properties. Cations with higher valence and mineral affinity showed a more significant contribution in inducing colloid aggregation, which was generally in accordance with the Schulze-Hardy rule and Hofmeister series. HA greatly increased the colloid stability by altering the surface electrostatic potential and steric effect. The Derjguin-Landau-Verwey-Overbeek (DLVO) model suggested that the electrostatic force between colloidal particles controlled the aggregation and destabilizing trend of colloid, and the theoretically calculated critical coagulation concentration was consistent with that determined from kinetic aggregation experiments. The roles of kaolinite colloid in driving Eu(III) transport varied under different conditions, and the transport behavior was highly correlated with the dispersion stability trend of colloid. These results can provide an enhanced understanding of the environmental fate of kaolinite colloid as well as commensal pollutants.

Nanoplastics are inevitably released into aquatic environments due to their extensive use and the continuous fragmentation of plastics. Therefore, it is imperative to understand the aggregation behaviours that determine the transport and fate of nanoplastics in aquatic environments. In this study, the effects of various metal cations, pH, aging and extracellular polymeric substances (EPS) on the aggregation of polystyrene nanoplastics (nano-PS) in aqueous solutions were systematically evaluated based on aggregation kinetics experiments and Derjaguin–Landau–Verwey–Overbeek (DLVO) theoretical calculation. The concentration, valence and hydration ability of metal cations jointly affected the aggregation of nano-PS. The critical coagulation concentration (CCC) of nano-PS was significantly higher than the ionic strengths in aquatic environments, indicating that the aggregation rate of nano-PS is relatively low in aquatic environments. The results of the aggregation kinetics experiments were consistent with DLVO theory, which showed that the energy barrier of nano-PS was dependent on electrostatic repulsion forces and van der Waals forces, and increased with pH. Nano-PS was artificially aged by UV-H₂O₂, which reduced the hydrophobic nature of the particle surfaces, consequently enhancing the stability of the nanoplastics. EPS (excreted from Chlorella pyrenoidosa) decreased the aggregation rates of nano-PS due to steric effects, which was confirmed by the extend DLVO model. Our results highlight the high stability of nano-PS in aquatic environments, which could help facilitate the evaluation of their environmental impact.

Thallium (TI) is one of the most toxic heavy metals and priority pollutant metals. The emerging TI environmental pollution worldwide has posed a great threat to human health. However, based on the World Health Organization (WHO), the risk and severity of adverse health effects of TI in the range of 5–500 μg/L are uncertain. Moreover, evidence regarding the adverse impacts of TI on children’s health is still insufficient. Herein, we aim to investigate the early adverse effects of TI on children’s health and provide references for the WHO to establish stricter safety limits of TI. From 2015 to 2019, urinary TI and many clinical laboratory parameters related to blood routine, hepatic, renal, myocardial, coagulation function and serum electrolyte were measured in six children aged 1–9 years. The urinary TI concentration ranged from 13.4 μg/L to 60.1 μg/L with a mean of 36.1 μg/L and a median of 34.8 μg/L in six children in 2015. Although only four children felt a little poor appetite, several laboratory abnormalities indicated early damage in liver, renal, and myocardial functions in all children in 2015. After treatment and following up for four years, although the children’s TI concentration decreased below 5 μg/L, their liver and renal functions did not completely recover, and their myocardial function worsened. Results indicated that impaired liver, renal, and myocardial functions were closely associated with elevated urinary TI concentration in children. Considering the increasing use of TI in high-technology industries and emerging TI environmental-contamination zones worldwide, establishing stricter safety limits of TI and paying more attention to the adverse health effects of TI on children are urgently required.We found that a relatively low concentration of thallium (13.4 μg/L to 60.1 μg/L) impaired liver, renal, and myocardial function in six children. After treatment and following up these children for four years, although their urinary TI concentration decreased below 5 μg/L, their liver and renal functions did not completely recover, and their myocardial function worsened.

Biodigested coffee processing wastewater (CPW) presents a high organic load and does not meet the limits imposed by legislation (namely in Brazil) for discharge into water bodies. Anaerobic digestion generally cannot provide a satisfactory organic matter reduction in CPW as a significant fraction of recalcitrant compounds still persists in the treated effluent. So, this study aims to find alternative ways to remove refractory organic compounds from this wastewater in order to improve the biodegradability and reduce the toxicity, which will allow its recirculation back into the anaerobic digester. Three treatment approaches (Fenton’s oxidation - Approach 1, Coagulation/flocculation (C/F) - Approach 2, and the combination of C/F with Fenton’s process - Approach 3) were selected to be applied to the biodigested CPW in order to achieve that objective.The application of the Fenton process under the optimal operating conditions (initial pH = 5.0; T = 55 °C, [Fe³⁺] = 1.8 g L⁻¹ and [H₂O₂] = 9.0 g L⁻¹) increased the biodegradability (the BOD₅:COD ratio raised from 0.34 ± 0.02 in biodigested CPW to 0.44 ± 0.01 after treatment) and eliminated the toxicity (0.0% of Vibrio fischeri inhibition) along with moderate removals of organic matter (51.3%, 55.7% and 39.7% for total organic carbon – TOC, chemical oxygen demand – COD and biochemical oxygen demand - BOD₅, respectively). The implementation of a coagulation/flocculation process upstream from Fenton’s oxidation, under the best operating conditions (pH 10–11 and [Fe³⁺] = 250 mg L⁻¹), also allowed to slightly increase the biodegradability (from 0.34 to 0.47) and reduce the toxicity, whereas providing a higher removal of organic matter (TOC = 76.2%, COD = 76.5 and BOD₅ = 66.3% for both processes together). Approach 1 and Approach 3 showed to be the best ones, implying similar operating costs (∼74 R$ m⁻³/∼17 € m⁻³) and constitute an attractive option for managing biodigested CPW.

The modified Fe₃O₄ nanoparticles were used as a support for the immobilization of horseradish peroxidase (HRP). The immobilized enzyme (HRP@Fe₃O₄) was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier-transform infrared spectrometer (FTIR), and vibration sample magnetometer (VSM). According to the results, the optimum concentration of glutaraldehyde (GA) and agitation time were 300 μL and 7 h. HRP was well loaded on the surface of the Fe₃O₄. There was no change in the crystal structure of HRP@Fe₃O₄ compared with Fe₃O₄. The removals of bisphenol A (BPA) and 17α-ethinylestradiol (EE2) using HRP@Fe₃O₄ had been investigated. The degradation efficiencies of BPA and EE2 catalyzed by HRP@Fe₃O₄ were higher than that of soluble HRP. In addition, HRP@Fe₃O₄ can be reused through magnetic separation. After the fifth repeated use, the removal efficiencies of BPA and EE2 were up to 56% and 48%, respectively. Batch studies of catalyzed oxidation and coagulation on the degradation of BPA and EE2 in the presence of humic acid (HA) were also investigated. The order of the removal efficiencies was HRP+PACl (polyaluminum chloride)+SDS (lauryl sodium sulfate)>HRP+PACl>HRP>HRP+PAM (Polyacrylamide)>HRP+PAM+SDS. The coagulation effect of HRP@Fe₃O₄ and PACl was better than that of HRP@Fe₃O₄ and PAM. The removals of BPA and EE2 were 90.3% and 64.5% by use HRP@Fe₃O₄ and PACl as coagulant, while the removals were 78.7% and 57.6% by use HRP@Fe₃O₄ and PAM as coagulant. SDS had a positive effect on PACl, while a negative effect on PAM. Moreover, the products generated by enzymatic oxidation reaction can be effectively removed after coagulation.