Radon is a natural radioactive gas present in the environment, which is considered as the second most important lung cancer cause worldwide. Currently, radon gas is under focus and was classified as contaminant of emerging concern, which is responsible for serious biological/health effects in human. In presented work we propose the numerical model and analysis method for radon diffusion rate measurements and radon transport parameters determination. The experimental setup for radon diffusion was built in a classical, two chamber configuration, in which the radon source and outlet reservoirs are separated by the sample being tested. The main difference with previously known systems is utilization of only one radon detector, what was achieved by a careful characterization of the Rn-222 source and development of a numerical model, which allows for exact determination of radon transport parameters by fitting simulated radon concentration profile in the outlet reservoir to experimental data. For verification of the developed system, several insulation materials commonly used in building industry and civil engineering, as well as, common building materials (gypsum, hardened cement paste, concrete) were tested for radon diffusion rate through these barriers. The results of radon transmittance, permeability and diffusion coefficients for investigated materials are in compliance with values known previously from the literature. The analysis method is fast and efficient, and requires measurement period varying from a dozen or so hours up to 2–3 days depending on material properties. The described method is entirely based on a numerical analysis of the proposed differential equation model using freely available SCILAB software and experimental data obtained during sample measurements.

High levels of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were detected in free-range eggs, and these levels reached a concentration of 29.84 ± 7.45 pg of WHO-TEQ/g of fat. This value exceeded the EU maximum permitted level of 2.5 pg of WHO-TEQ/g of fat for PCDD/F congeners by twelve-fold. A chemical analysis (HRGC-HRMS) revealed elevated amounts of OCDD, OCDF, HxCDD, HpCDD and HpCDF. During the investigation, samples of feed, soil, wall scrapings, wooden ceiling of the henhouse and tissues from laying hens were examined for dioxin contents (30 samples altogether). The long and complicated investigation found that the source of dioxins in the poultry farm was pentachlorophenol-treated wood, which was used as structural components in the 40-year-old farm building adapted to a henhouse. The wooden building material contained PCDD/Fs at a concentration of 3922.60 ± 560.93 pg of WHO-TEQ/g and 11.0 ± 2.8 μg/kg of PCP. The potential risk associated with dioxin intake was characterized by comparing the theoretically calculated weekly and monthly intakes with the toxicological reference values (TRVs), namely the Tolerable Weekly Intake (TWI) and Provisional Tolerable Monthly Intake (PTMI) values of 14 pg of WHO-TEQ/kg of bw and 70 pg of WHO-TEQ/kg of bw, respectively. The intake of dioxins estimated for high egg consumers (approximately 5–6 eggs/week) exceeded the TWI and PTMI values, which may pose a risk of delayed adverse health effects. The estimated dose of PCDD/Fs and DL-PCBs for children consuming 5 eggs per week exceeded the TWI by as much as 450% because of their nearly 5-fold-lower body weight. Although the dioxin intake estimated for the average consumption of eggs in the general population did not exceed any of the TRVs applied (58.7% TWI and 51.1% PTMI), such a situation should be considered unacceptable from a public health perspective because eggs are not the only source of these contaminants.

Urban metabolism refers to the assessment of the amount of resources produced and consumed by urban ecosystems. It has become an important tool to understand how the development of one city causes impacts to the local and regional environment and to support a more sustainable urban design and planning. Therefore, the purpose of this paper was to measure the changes in material and energy use occurred in the city of Curitiba (Brazil) between the years of 2000 and 2010. Results reveal better living conditions and socioeconomic improvements derived from higher resource throughput but without complete disregard to environmental issues. Food intake, water consumption and air emissions remained at similar levels; energy use, construction materials and recycled waste were increased. The paper helps illustrate why it seems more adequate to assess the contribution a city makes to sustainable development than to evaluate if one single city is sustainable or not.

This study investigated by the moss-bag approach the pattern of air dispersed elements in 12 coupled indoor/outdoor exposure sites, all located in urban and rural residential areas. The aims were to discriminate indoor vs. outdoor element composition in coupled exposure sites and find possible relation between moss elemental profile and specific characteristics of each exposure site.Elements were considered enriched when in 60% of the sites, post-exposure concentration exceeded pre-exposure concentration plus two folds the standard deviation. Of the 53 analyzed elements, 15 (As, B, Ca, Co, Cr, Cu, Mn, Mo, Ni, Sb, Se, Sn, Sr, V, Zn) were enriched in moss exposed outdoor, whereas a subset of 7 elements (As, B, Cr, Mo, Ni, Se, V) were enriched also in indoor moss samples. The cluster analysis of the sites based on all elements, clearly separated samples in two groups corresponding to mosses exposed indoor and outdoor, with the latter generally exceeding the first. Among outdoor sites, urban were most impacted than rural; whereas other factors (e.g., heating and cooking systems, building material, residence time and family life style) could affect element profile of indoor environments. Based on the indoor/outdoor ratio, As derived from outdoor and indoor sources, B, Mo and Se were enriched mostly in outdoor sites; Ni, Cr and V were specifically enriched in most indoor samples, supporting the presence of indoor emitting sources for these elements. A PCA of all indoor sites based on enriched elements and site characteristics showed that traffic affected indoor pollution in urban areas. The moss bag approach provided useful information for a global assessment of human exposure.

The distributions of organophosphate flame retardants (OPFRs) in various size fractions of indoor dust samples from homes (H; n = 18) and building material markets (B; n = 7) in the Rhine/Main region of Germany were investigated. Three particle size fractions (F1: 150–200 μm, F2: 63–150 μm, and F3: <63 μm) and bulk dust (BD) subsamples (<200 μm) of each sample were analyzed for 10 OPFRs. On average, the total OPFR concentrations (∑10OPFR) in bulk dust and all three size fractions from building material markets were 133, 153, 196, and 88.0 μg/g in subsamples B-BD, B-F1, B-F2, and B-F3. These concentrations were at least five times higher than those in bulk dust and all three size fractions from homes, with values of 19.3, 17.2, 19.5, and 18.7 μg/g for subsamples H-BD, H-F1, H-F2, and H-F3, respectively. Tris(2-chloroisopropyl)phosphate (TCIPP) was the dominant congener in dust from building material markets, contributing over 91% to the ∑10OPFR of B-BD and all particle size fractions. Meanwhile, both tris(2-butoxyethyl)phosphate (TBOEP) and TCIPP were abundant in dust from homes, respectively contributing 28%–41% and 31%–43% to the ∑10OPFR of H-BD and all particle size fractions. Most of the OPFR concentrations showed no consistent trend with particle size. However, TCIPP was more likely to be enriched in F2. Microscopic examination indicated that TCIPP in indoor dust mainly originated from abraded fragments of commercial products. In contrast, TBOEP accumulated in F3, related to direct transfer of floor-care products to fine dust particles. The concentrations of OPFRs were not significantly correlated with total organic carbon contents in any particle size fraction. However, evaluation of their mass contributions showed that more than 85% of OPFRs accumulated in particles smaller than 150 μm, indicating that this particle size fraction is most suitable for monitoring of OPFRs.

Nanomaterials are increasingly being used to improve the properties and functions of common building materials. A new type of self-cleaning cement incorporating TiO2 nanomaterials (TiO2-NMs) with photocatalytic properties is now marketed. This promising cement might provide air pollution-reducing properties but its environmental impact must be validated. During cement use and aging, an altered surface layer is formed that exhibits increased porosity. The surface layer thickness alteration and porosity increase with the cement degradation rate. The hardened cement paste leaching behavior has been fully documented, but the fate of incorporated TiO2-NMs and their state during/after potential release is currently unknown. In this study, photocatalytic cement pastes with increasing initial porosity were leached at a lab-scale to produce a range of degradation rates concerning the altered layer porosity and thickness. No dissolved Ti was released during leaching, only particulate TiO2-NM release was detected. The extent of release from this batch test simulating accelerated worst-case scenario was limited and ranged from 18.7 ± 2.1 to 33.5 ± 5.1 mg of Ti/m2 of cement after 168 h of leaching. TiO2-NMs released into neutral aquatic media (simulate pH of surface water) were not associated or coated by cement minerals. The TiO2-NM release mechanism is suspected to start from freeing of TiO2-NMs in the altered layer pore network due to partial cement paste dissolution followed by diffusion into the bulk pore solution to the surface. The extent of TiO2-NM release was not solely related to the cement degradation rate.

Five cement- and five lime-based building materials were examined in an environmental chamber for their emissions of Volatile Organic Compounds (VOCs). Typical VOCs were below detection limits, whereas not routinely analysed VOCs, like neopentyl glycol (NPG), dominated the cement-based products emissions, where, after 72 h, it was found to occur, in levels as high as 1400 μg m⁻³, accounting for up to 93% of total VOCs. The concentrations of NPG were not considerably changed between the 24 and 72 h of sampling. The permeability of building materials was assessed through experiments with a dual environmental chamber; it was shown that building materials facilitate the diffusion of chemicals through their pores, reaching equilibrium relatively fast (6 h).

The objective of the study reported in this paper was to assess the quality of harvested rainwater on the basis of the roofing materials used and the presence of lichens/mosses on the roofing surface. Four pilot structures with different roofing materials (i.e., wooden shingle tiles, concrete tiles, clay tiles [Gi-Wa] and galvanized steel) were installed in a field. The galvanized steel was found to be the most suitable for rainwater harvesting applications, with their resulting physical and chemical water quality parameters meeting the Korean guidelines for drinking water quality (e.g., pH (5.8–8.5), TSS <500 mg/L, NO₃ ⁻ < 10 mg/L, SO₄ ²⁻ < 200 mg/L, Al < 0.2 mg/L, Cu < 1 mg/L, Fe < 0.3 mg/L, Pb < 0.05 mg/L, Zn < 1 mg/L, and E. coli (No detection)). In the galvanized steel case, the relatively high water quality was probably due to ultraviolet light and the high temperature effectively disinfecting the harvested rainwater. It was also found that the presence of lichens and mosses may adversely affect the physical, chemical and microbiological quality of rainwater.

An urban soil chronosequence in downtown Detroit, MI was studied to determine the effects of time on pedogenesis and heavy metal sequestration. The soils developed in fill derived from mixed sandy and clayey diamicton parent materials on a level late Pleistocene lakebed plain under grass vegetation in a humid-temperate (mesic) climate. The chronosequence is comprised of soils in vacant lots (12 and 44 years old) and parks (96 and 120 years old), all located within 100m of a roadway. An A-horizon 16cm thick with 2% organic matter has developed after only 12 years of pedogenesis. The 12 year-old soil shows accelerated weathering of iron (e.g. nails) and cement artifacts attributed to corrosion by excess soluble salts of uncertain origin. Carbonate and Fe-oxide are immobilizing agents for heavy metals, hence it is recommended that drywall, plaster, cement and iron artifacts be left in soils at brownfield sites for their ameliorating effects.

This paper attempts to evaluate the positive effects of vegetation with a multi-scale approach: an urban and a building scale. Monitoring the urban heat island in four areas of New York City, we have found an average of 2 °C difference of temperatures between the most and the least vegetated areas, ascribable to the substitution of vegetation with man-made building materials. At micro-scale, we have assessed the effect of surface albedo on climate through the use of a climatological model. Then, using the CO₂ equivalents as indicators of the impact on climate, we have compared the surface albedo, and the construction, replacement and use phase of a black, a white and a green roof. By our analyses, we found that both the white and the green roofs are less impactive than the black one; with the thermal resistance, the biological activity of plants and the surface albedo playing a crucial role.