The photocatalytic degradation of dyes (Allura Red AC and Brilliant Blue FCF) in water using ultraviolet light-emitting diodes (UV-LED) and an immobilized titanium dioxide (TiO₂) as a photocatalyst was investigated using a novel bench-top Teflon® reactor. This reactor has been uniquely designed to contain low-powered UV-LEDs combined with TiO₂ immobilized substrates. A sol-gel method was used to anneal TiO₂ to three different substrates: standard microscope quartz slides, quartz cylinders, and borosilicate beads. Scanning electron microscopy (SEM), Raman spectroscopy, and mass comparisons techniques were performed for TiO₂ characterization. High-resolution images confirmed the presence and morphology of TiO₂ on the substrates. These analyses demonstrated the TiO₂ coating was uniform and predominantly had the anatase crystalline phase structure. The slide had the largest individual TiO₂ surface area of 0.187 mg cm⁻². Results indicated the size, shape, packing, and stirring properties were factors that determine overall photocatalytic properties and degradation inside the reactor. The adjusted rate constants for an ideal completely mixed batch reactor (CMBR) were 1.69 * 10⁻³, 5.39 * 10⁻³, and 4.46 * 10⁻³ min⁻¹ for the slides, beads, and cylinders, respectively. Beads were the best-performing substrate as determined by the greatest degradation rate for the model organic compound, Allura Red AC. The beads and cylinders showed 58 and 51% degradation of Allura Red AC, respectively. Actinometry experiments revealed cylinders had the largest fluence rate of 0.0782 J·L⁻¹ s⁻¹. Optimization of the sol-gel application method and reactor operating parameters was performed to maximize the degradation rate and the overall degradation of Allura Red AC. Electric energy per order (EEO) was calculated and optimized at 9.20, 10.5, and 12.7 kWh·m⁻³ order⁻¹ for the glass beads, cylinders, and slides, respectively. Graphical abstract ᅟ

Pipe section reactor (PSR) is a well-controlled laboratory reactor, which is used to simulate the water quality variations in drinking water distribution systems. However, the hydraulics condition within PSR, which is an essential prerequisite of the water quality studies, still remains unclear. Consequently, the objective of this study is to analyze the hydraulic conditions within PSR by means of a computational fluid dynamics (CFD) approach. The influences of configuration parameters on the hydraulic conditions were tested including propeller diameter, inclined angle of the propeller, distance between the top and inner cylinder, distance between the bottom and inner cylinder, outer cylinder length, baffle length, number of the baffles, rotational speed of the propeller, and inner and outer cylinder diameters. According to the CFD analysis, an optimal structure of PSR was suggested. The data presented here could facilitate the PSR application and improve the simulation of water quality in distribution systems.

In this paper, the effect of injection pressure on the performance, emission, and combustion characteristics of a diesel-acetylene fuelled single cylinder, four-stroke, direct injection (DI) diesel engine with a rated power of 3.5 kW at a rated speed of 1500 rpm was studied. Experiments were performed in dual-fuel mode at four different injection pressures of 180, 190, 200, and 210 bar with a flow rate of 120 LPH of acetylene and results were compared with that of baseline diesel operation. Experimental results showed that highest brake thermal efficiency of 27.57% was achieved at injection pressure of 200 bar for diesel-acetylene dual-fuel mode which was much higher than 23.32% obtained for baseline diesel. Carbon monoxide, hydrocarbon, and smoke emissions were also measured and found to be lower, while the NO ₓ emissions were higher at 200 bar in dual fuel mode as compared to those in other injection pressures in dual fuel mode and also for baseline diesel mode. Peak cylinder pressure, net heat release rate, and rate of pressure rise were also calculated and were higher at 200 bar injection pressure in dual fuel mode.

The present work is intended to investigate the emission characteristics of neat cashew nut shell methyl ester (CNSME100) by adding pentanol at two different proportions and compared with the baseline diesel. CNSME100 is prepared by the conventional transesterification process. CNSME100 is chosen due to its non-edible nature. Pentanol is chosen as an additive because of its higher inbuilt oxygen content and surface to volume ratio which reduces the drawbacks of neat CNSME100. Emission characteristics were carried out in single cylinder naturally aspirated CI engine fuelled with neat cashew nut shell methyl ester (CNSME), cashew nut shell methyl ester and pentanol by 10% volume (CNSME90P10), cashew nut shell methyl ester and pentanol by 20% volume (CNSME80P20), and diesel. This work also aims to investigate the feasibility of operating an engine fuelled with neat methyl ester and alcohol blends. Experimental results showed that by blending higher alcohol to neat cashew nut shell methyl ester reduces the emissions significantly. It is also found that the emission from neat methyl ester and pentanol blends is lesser than diesel at all loads.

A gas standard mixture containing 22 chlorinated hydrocarbons in high purity nitrogen was prepared using a two-step weighing method and a gasifying apparatus developed in-house. The concentration of each component was determined using a gas chromatograph with flame ionization detection (GC/FID). Linear regression analysis of every component was performed using the gas standard mixture with concentrations ranging from 1 to 10 μmol/mol, showing the complete gasification of volatile organic compound (VOCs) species in a selected cylinder. Repeatability was also examined to ensure the reliability of the preparation method. In addition, no significant difference was observed between domestic treated and imported treated cylinders, which were conducive to reduction of the cost of raw materials. Moreover, the results of stability testing at different pressures and long-term stability tests indicated that the gas standard at 1 μmol/mol level with relative expanded uncertainties of 5% was stable above 2 MPa for a minimum of 12 months. Finally, a quantity comparison was conducted between the gas standard and a commercial gas standard from Scott Specialty Gases (now Air Liquide America Specialty Gases). The excellent agreement of every species suggested the favorable accuracy of our gas standard. Therefore, this reference material can be applied to routine observation of VOCs and for other purposes.

One of the most important sources of pollution caused by metals, if not the most important, is mining. Metal pollution is covert, persistent and irreversible. For this reason, soil metal pollution has become a severe problem in many parts of the world. The aim of this study was to observe which combination of amendments (compost + biochar or technosol + biochar) combined with Brassica juncea L. was best at reducing the assimilable contents of Cu, and which also increased to a lesser extent the contents of other metals (Ni, Pb, Zn) found in these amendments. We also studied the phytoremediation capacity of brassicas in these amendments. The experiment was carried out using 45-cm-deep cylinders over and 11-month period, with soil from the settling pond in the depleted copper mine located in Touro (Galicia, north-west Spain). At depth 0–15 cm, the settling pond soil (S) had a higher CaCl₂-extractable Cu, Pb, and Ni concentration, at the three time periods measured (time 1 = 3 months, time 2 = 7 months, time 3 = 11 months). The settling pond soil + technosol + biochar and vegetated with Brassica juncea L. (STBP) had the highest CaCl₂-extractable concentrations of Zn over time. In general terms, the most effective treatment for reducing the phytoavailable contents of Cu, Pb, Ni and Zn was the treatment using compost +b iochar + Brassica juncea L. In the two treatments applied, Brassica juncea L. had a good phytostabilisation capacity.

A numerical study was carried out to study the effect of various combustion bowl parameters on the performance behavior, combustion characteristics, and emission magnitude on a single cylinder diesel engine. A base combustion bowl and 11 different combustion bowls were created by varying the aspect ratio, reentrancy ratio, and bore to bowl ratio. The study was carried out at engine rated speed and a full throttle performance condition, without altering the compression ratio. The results revealed that the combustion bowl parameters could have a huge impact on the performance behavior, combustion characteristics, and emission magnitude of the engine. The bowl parameters, namely throat diameter and toroidal radius, played a crucial role in determining the performance behavior of the combustion bowls. It was observed that the combustion bowl parameters, namely central pip distance, throat diameter, and bowl depth, also could have an impact on the combustion characteristics. And throat diameter and toroidal radius, central pip distance, and toroidal corner radius could have a consequent effect on the emission magnitude of the engine. Of the different combustion bowls tested, combustion bowl 4 was preferable to others owing to the superior performance of 3% of higher indicated mean effective pressure and lower fuel consumption. Interestingly, trade-off for NO ₓ emission was higher only by 2.85% compared with the base bowl. The sensitivity analysis proved that bowl depth, bowl diameter, toroidal radius, and throat diameter played a vital role in the fuel consumption parameter and emission characteristics even at the manufacturing tolerance variations.

Exploring new renewable energy sources as a substitute of petroleum reserves is necessary due to fulfilling the oncoming energy needs for industry and transportation systems. In this quest, a lot of research is going on to expose different kinds of new biodiesel sources. The non-edible oil from candlenut possesses the potential as a feedstock for biodiesel production. The present study aims to produce biodiesel from crude candlenut oil by using two-step transesterification process, and 10%, 20%, and 30% of biodiesel were mixed with diesel fuel as test blends for engine testing. Fourier transform infrared (FTIR) and gas chromatography (GC) were performed and analyzed to characterize the biodiesel. Also, the fuel properties of biodiesel and its blends were measured and compared with the specified standards. The thermal stability of the fuel blends was measured by thermogravimetric analysis (TGA) and differential scan calorimetry (DSC) analysis. Engine characteristics were measured in a Yanmar TF120M single cylinder direct injection (DI) diesel engine. Biodiesel produced from candlenut oil contained 15% free fatty acid (FFA), and two-step esterification and transesterification were used. FTIR and GC remarked the biodiesels’ existing functional groups and fatty acid methyl ester (FAME) composition. The thermal analysis of the biodiesel blends certified about the blends’ stability regarding thermal degradation, melting and crystallization temperature, oxidative temperature, and storage stability. The brake power (BP), brake specific fuel consumption (BSFC), and brake thermal efficiency (BTE) of the biodiesel blends decreased slightly with an increasing pattern of nitric oxide (NO) emission. However, the hydrocarbon (HC) and carbon monoxides (CO) of biodiesel blends were found decreased.

The present study deals with performance, emission and combustion studies in a single cylinder CI engine with lower and higher alcohol fuel synergies with biofuel blends and exhaust treatment system. Karanja oil methyl ester (KOME), widely available biofuel in India, and orange oil (ORG), a low carbon biofuel, were taken for this study, and equal volume blend was prepared for testing. Methanol (M) and n-pentanol (P) was taken as lower and higher alcohol and blended 20% by volume with KOME-ORG blend. Activated carbon-based exhaust treatment indigenous system was designed and tested with KOME-ORG + M20 and KOME-ORG + P20 blend. The tests were carried out at various load conditions at a constant speed of 1500 rpm. The study revealed that considering performance, emission and combustion studies, KOME-ORG + M20 + activated carbon are found optimum in reducing NO, smoke and CO₂ emission. Compared to KOME, for KOME-ORG + M20 + activated carbon, NO emission is reduced from 10.25 to 7.85 g/kWh, the smoke emission is reduced from 49.4 to 28.9%, and CO₂ emission is reduced from 1098.84 to 580.68 g/kWh. However, with exhaust treatment system, an increase in HC and CO emissions and reduced thermal efficiency is observed due to backpressure effects.

The study represents a comprehensive analysis of engine exhaust emission variation from a compression ignition (CI) diesel engine fueled with diesel-biodiesel blends. Biodiesel used in this investigation was produced through transesterification procedure from Moringa oleifera oil. A single cylinder, four-stroke, water-cooled, naturally aspirated diesel engine was used for this purpose. The pollutants from the exhaust of the engine that are monitored in this study are nitrogen oxide (NO), carbon monoxide (CO), hydrocarbon (HC), and smoke opacity. Engine combustion and performance parameters are also measured together with exhaust emission data. Some researchers have reported that the reason for higher NO emission of biodiesel is higher prompt NO formation. The use of antioxidant-treated biodiesel in a diesel engine is a promising approach because antioxidants reduce the formation of free radicals, which are responsible for the formation of prompt NO during combustion. Two different antioxidant additives namely 2,6-di-tert-butyl-4-methylphenol (BHT) and 2,2′-methylenebis(4-methyl-6-tert-butylphenol) (MBEBP) were individually dissolved at a concentration of 1% by volume in MB30 (30% moringa biodiesel with 70% diesel) fuel blend to investigate and compare NO as well as other emissions. The result shows that both antioxidants reduced NO emission significantly; however, HC, CO, and smoke were found slightly higher compared to pure biodiesel blends, but not more than the baseline fuel diesel. The result also shows that both antioxidants were quite effective in reducing peak heat release rate (HRR) and brake-specific fuel consumption (BSFC) as well as improving brake thermal efficiency (BTE) and oxidation stability. Based on this study, antioxidant-treated M. oleifera biodiesel blend (MB30) can be used as a very promising alternative source of fuel in diesel engine without any modifications.