Humic-like substances (HULIS) are complex mixtures that are highly associated with brown carbon (BrC) and are important components of biomass burning (BB) emissions. In this study, we investigated the light absorption, emission factors (EFs), and amounts of HULIS emitted from the simulated burning of 27 types of regionally important rainforest biomass in Southeast Asia. We observed that HULIS had a high mass absorption efficiency at 365 nm (MAE₃₆₅), with an average value of 2.6 ± 0.83 m² g⁻¹ C. HULIS emitted from BB accounted for 65% ± 13% of the amount of water-soluble organic carbon (WSOC) and 85% ± 10% of the light absorption of WSOC at 365 nm. The EFs of HULIS from BB averaged 2.3 ± 2.1 g kg⁻¹ fuel, and the burning of the four vegetation subtypes (herbaceous plants, shrubs, evergreen trees, and deciduous trees) exhibited different characteristics. The differences in EFs among the subtypes were likely due to differences in lignin content in the vegetation, the burning conditions, or other factors. The light absorption characteristics of HULIS were strongly associated with the EFs. The annual emissions (minimum–maximum) of HULIS from BB in this region in 2016 were 200–371 Gg. Furthermore, the emissions from January to April accounted for 99% of the total annual emissions of HULIS, which is likely the result of the burning activities during this season. The most significant emission regions were Cambodia, Burma, Thailand, and Laos. This study, which evaluated emissions of HULIS by simulating open BB, contributes to a better understanding of the light-absorbing properties and regional budgets of BrC in this region.

Exposure to air pollution has been linked to elevated blood pressure (BP) and hypertension, but most research has focused on short-term (hours, days, or months) exposures at relatively low concentrations. We examined the associations between long-term (3-year average) concentrations of outdoor PM₂.₅ and household air pollution (HAP) from cooking with solid fuels with BP and hypertension in the Prospective Urban and Rural Epidemiology (PURE) study. Outdoor PM₂.₅ exposures were estimated at year of enrollment for 137,809 adults aged 35–70 years from 640 urban and rural communities in 21 countries using satellite and ground-based methods. Primary use of solid fuel for cooking was used as an indicator of HAP exposure, with analyses restricted to rural participants (n = 43,313) in 27 study centers in 10 countries. BP was measured following a standardized procedure and associations with air pollution examined with mixed-effect regression models, after adjustment for a comprehensive set of potential confounding factors. Baseline outdoor PM₂.₅ exposure ranged from 3 to 97 μg/m³ across study communities and was associated with an increased odds ratio (OR) of 1.04 (95% CI: 1.01, 1.07) for hypertension, per 10 μg/m³ increase in concentration. This association demonstrated non-linearity and was strongest for the fourth (PM₂.₅ > 62 μg/m³) compared to the first (PM₂.₅ < 14 μg/m³) quartiles (OR = 1.36, 95% CI: 1.10, 1.69). Similar non-linear patterns were observed for systolic BP (β = 2.15 mmHg, 95% CI: −0.59, 4.89) and diastolic BP (β = 1.35, 95% CI: −0.20, 2.89), while there was no overall increase in ORs across the full exposure distribution. Individuals who used solid fuels for cooking had lower BP measures compared to clean fuel users (e.g. 34% of solid fuels users compared to 42% of clean fuel users had hypertension), and even in fully adjusted models had slightly decreased odds of hypertension (OR = 0.93; 95% CI: 0.88, 0.99) and reductions in systolic (−0.51 mmHg; 95% CI: −0.99, −0.03) and diastolic (−0.46 mmHg; 95% CI: −0.75, −0.18) BP. In this large international multi-center study, chronic exposures to outdoor PM₂.₅ was associated with increased BP and hypertension while there were small inverse associations with HAP.

One of the most important reasons for the controversy over the development of nuclear energy is the proper disposal of spent fuel. Separation of actinide and lanthanide ions is an important part of safe long-term storage of radioactive waste. Herein, a three-dimensional (3D) graphene-based macrostructure (GOCS) was utilized to remove actinide thorium and lanthanide europium ions from aqueous solutions. The adsorption of Eu(III) and Th(IV) on the GOCS was evaluated as a function of adsorption time, solution pH, initial ion concentrations, and ionic strength. The experimentally determined maximum adsorption capacities of this GOCS for Eu(III) (pH 6.0) and Th(IV) (pH 3.0) are as high as 150 and 220 mg/g, respectively. By using Fourier transformation infrared (FT-IR), X-ray photoelectron (XPS), and extended X-ray absorption fine structure (EXAFS) spectroscopy, we concluded that the Eu(III) and Th(IV) adsorption was predominantly attributed to the inner-sphere coordination with various oxygen- and nitrogen-containing functional groups on GOCS surfaces. Our selective adsorption results demonstrate that the actinide and lanthanide ions can be effectively separated from transition metal ions. This study provides new clues to the overall recycling of actinide and lanthanide ions in radioactive environmental pollution treatments.

Concrete, a cement-based product is the highest manufactured and second highest consumed product after water on earth. Across the world, production of cement is the most energy and emission intensive industry hence, the cement industry is currently under pressure to reduce greenhouse gases emissions (GHGEs). However, reducing the GHGEs of the cement industry especially for developing country like India is not an easy task. Cement manufacturing industry needs to focus on significant climate change mitigation strategies to reduce the GHGEs to sustain its production. This study aims at identifying significant climate change mitigation strategies of the cement manufacturing industry in the context of India. Extant literature review and expert opinion are used to identify climate change mitigation strategies of the cement manufacturing industry. In the present study, a model projects by applying both AHP and DEMATEL techniques to assess the climate change mitigation strategies of the cement industry. The AHP technique help in establishing the priorities of climate change mitigation strategies, while the DEMATEL technique forms the causal relationships among them. Through AHP, the results of this research demonstrate that Fuel emission reduction is on top most priority while the relative importance priority of the main remaining factors is Process emission reduction - Electric energy-related emission - Emission avoidance and reduction - Management mitigation measures. The findings also indicate that the main factors, Process emission reduction, and Fuel emission reduction are categorized in cause group factors, while the remaining factors, Electric energy-related emission, Emission avoidance and reduction and Management mitigation measures are in effect group factors. Present model will help supply chain analysts to develop both short-term and long-term decisive measures for effectively managing and reducing GHGEs.

Faced with the unavoidable reality of the emission of pollutant gases by vessels both while sailing and when performing in-port manoeuvres, the international community has devised an extensive set of rules to limit greenhouse gas emissions and the emission of other pollutants which are bad for our health. In order to make these reductions in the emissions, the areas addressed are the engine regime or speed control, the quality of the fuel used, the state of conservation of the vessel and its hull or the time taken to perform the manoeuvres of mooring and unmooring. One factor which is having a strong influence on this last aspect is the installation in commercial ports of Automatic Mooring Systems using suction cups (AMS). These devices, which help to reduce considerably the time required to perform the mooring and unmooring manoeuvres, allow the times taken in operations for making steady a vessel to land and of releasing it to sail away to be reduced from some tens of minutes to a few seconds. The aim of this work is to verify the effect of the AMS on the emission of pollutant gases in the surroundings of the installations devoted to Ro-Ro/Pax vessel traffic. In particular, will focus on the CO2 emissions produced by vessels during mooring operations using two different calculation methodologies (EPA and ENTEC), first when using traditional mooring methods as a means of securing the vessel to the dock and second when using only the AMS, to finally carry out a comparison of the results. Will conclude with a discussion on the values of the reduction in emissions obtained and the advantages of installing AMS in commercial ports. In the RoRo/Pax terminals in which the AMS is installed and operating, a reduction in CO2 emissions of 97% has been estimated.

In this study, the effects of descent flight path angle (between 1.25° and 4.25°) on aircraft gaseous emissions (carbon monoxide, total hydrocarbons and nitrogen oxides) are explored using actual flight data from aircraft flight data recording system and emissions indices from the International Civil Aviation Organization. All emissions parameters are corrected to flight conditions using Boeing Fuel Flow Method2, where the ambient air pressure, temperature and humidity data are obtained from long-term radiosonde data measured close to the arrival airport. The main findings highlight that the higher the flight path angle, the higher the emission indices of CO and HC, whereas the lower the emissions index of NOx and fuel consumption. Furthermore, during a descent, a heavier aircraft tends to emit less CO and HC, and more NOx. For a five-tonne aircraft mass increase, the average change in emissions indices are found to be −4.1% and −5.7% (CO), −5.4% and −8.2% (HC), and +1.1% and +1.6% (NOx) for high and low flight path angle groups, respectively. The average emissions indices for CO, HC and NOx during descent are calculated to be 24.5, 1.7 and 5.6 g/kg of fuel, whereas the average emissions for descending from 32,000 ft (9.7 km) and 24,000 ft (7.3 km) are calculated to be 7–8 kg (CO), ∼0.5 kg (HC) and ∼3 kg (NOx).

Seven organophosphorus compounds (OPs) were measured in urban fine and coarse particulate matter (PM) collected from two sites of Nanjing (XCNUC), China and Islamabad (APHSP), Pakistan. The fine PM mass at APHSP site was significantly higher (p = 0.005) in the spring (mean 22.5 μg/m³) than in the summer (mean 12.7 μg/m³). The total concentration, ∑⁷OPs, of samples collected at APHSP was found significantly higher in coarse (range 672–47621 pg/m³) than in fine PM (range 1200–15213 pg/m³); while ∑⁷OPs from XCNUC in fine (range 1696–15063 pg/m³) and coarse PM (range 2053–5379 pg/m³) were statistically different in samples during summer, based on two-sample t-test at 0.05 confidence interval. Seasonally, ∑⁷OPs was found to be higher in the samples of Nanjing (9510 ± 3633 pg/m³) in the summer than in the spring. In contrast, the samples of Islamabad had higher ∑⁷OPs (25558 ± 16255 pg/m³) in the spring than in the summer. Tri(chloropropyl) phosphate (TCEP) was found at higher concentration than any other OPs in the samples from the XCNUC site. Triphenyl phosphate (TPhP) was found at extremely high levels from APHSP, which may attributed to its use in jet fuel. Most of the ∑OPs concentrations were found significantly different in both PMs at both sites due to their diverse sources. Both sites showed strong correlation of ∑OPs with TCEP in both PMs, indicating similar mode of transfer from sources like plastics, lacquer, paint, glue, industrial processes and foam fillers. Relative abundance of OPs in fine and coarse PM differs amongst OP congeners and concerning seasons, with these variations attributed to different mechanisms of mass transfer such as volatilization, condensation and abrasions. Moreover, triphenylphosphine oxide (TPPO) has been reported in outdoor PMs. This is the first study on the occurrence of OPs in atmospheric fine and coarse PM and their seasonal variation from Pakistan and China.

This study investigated ambient volatile organic compounds (VOCs) and assessed excess health risks for child, adult and elderly populations in a residential area near a large-scale petrochemical complex in central Taiwan. A total of 155 daily VOC samples were collected in canisters from nine sites in spring, summer and winter during 2013–2014. We used a positive matrix factorization (PMF) model incorporating a conditional probability function (CPF) to quantify the potential sources of VOCs with the influences of local source directions. We then evaluated the non-cancer and cancer risks of specific VOCs with probabilistic distributions by performing a Monte-Carlo simulation for the child, adult, and elderly populations. Most of the VOCs were higher in summer than in winter or spring for the sampling sites. The presence of vinyl acetate, chloroethene, and 1,2-dichloroethane were significantly high within a 5-km radius of the petrochemical complex. Four potential sources of ambient VOCs, industrial emission (49.2%–63.6%), traffic-related emission (13.9%–19.1%), fuel evaporation (12.3%–16.9%), and aged emission (10.2%–14.8%), were identified. The cancer risk of ambient VOC exposure was mainly attributed to the industrial source in the study area, while the non-cancer risk was of less concern. Benzene associated with fuel evaporation resulted in the highest cancer risk (4.1 × 10−5−5.5 × 10−5) as compared to that of the other toxic VOCs.