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Seasonal Variation and Spatial Distribution of Uranium in Sources of Water in Tonk District of Rajasthan, India
2024
Bairwa, Avinash | Gupta, Ashok | Mishra, Vivek | Sahoo, Sunil | Tiwar, Shailesh | Menaria, Tejpal | Gupta, Kalpana
This study was undertaken to evaluate concentration of Uranium (U) in the drinking water of the Tonk district of Rajasthan (India). The main objective of the study is to determine the distribution of Uranium concentration and the geochemical behavior of Uranium in pre-monsoon (PRM) and post-monsoon (POM) drinking water samples. Uranium was measured by LED fluorimeter. Total 318 drinking water samples were collected for both seasons. It is observed that the water quality of all the samples is within the limits prescribed by WHO (30 µg/L) except a few, and can be used for domestic purposes. The Uranium concentration was found to be in the range 0.21 to 173.72 µg/L with a mean value of 8.58 µg/L in pre-monsoon and 0.21 to 162.34 µg/L with a mean value of 11.22 µg/L in post-monsoon samples. The geochemistry of the study area shows rock-water interaction. The order of average anionic concentration is found to be HCO3 – > Cl – > SO4 2– > NO3 –. Although no definite trend of seasonal variation in the concentration of U was observed, large samples have higher Uranium concentrations in post-monsoon than pre-monsoon.
اظهر المزيد [+] اقل [-]Need for an Evolved Groundwater Justice in Rural Areas of Uttar Pradesh, India
2024
V. S. Tari, N. Siddiqui, D. Rathi, N. N. Siddiqui and D. K. Wahyuni
As groundwater is the primary element of life, countries all over the world are experimenting with legal reforms. The degree to which law reforms combine justice and sustainability is a crucial question. In response to this question, the present article focuses on a case study of Uttar Pradesh, India. Our response is based on a content analysis of the Uttar Pradesh Groundwater (Management and Regulation) Act, 2019, and the Uttar Pradesh Groundwater (Management and Regulation) Rules, 2020. Three conclusions emerged from our investigation. First, the 2019 Groundwater Act and the 2020 Draft Groundwater Rules are primarily motivated by concerns about resource sustainability, particularly in areas where the water table is steadily declining. Still, neither the 2019 Groundwater Act nor the 2020 Draft Groundwater Rules propose any proactive groundwater justice measures. Second, we suggest that some locally defined basic elements are critical in supporting sustainability and – to a lesser extent – groundwater justice. These characteristics include a community’s ability to (1) recognize a crisis and show a willingness to address it; (2) establish a rule-bound community groundwater resource; (3) demonstrate leadership and a sense of community; and (4) make use of awareness, information, and knowledge. Our third conclusion is that there is a need for community practices and state-led groundwater law to co-evolve; this co-evolution has the potential to create groundwater arrangements that support both groundwater justice and sustainability.
اظهر المزيد [+] اقل [-]Eco-Engineered Low-Cost Carbosorbent Derived from Biodegradable Domestic Waste for Efficient Total Chromium Removal from Aqueous Environment: Spectroscopic and Adsorption Study
2024
Vandana Saxena, Ashish Kumar Singh, Atul Srivastava and Anushree Srivastava
Chromium contamination in water bodies poses severe risks to both the environment and human health. This research introduces an innovative solution to this challenge by creating a vapor-activated carbosorbent from biodegradable household waste. The efficacy of this adsorbent in removing total chromium through batch methods from aqueous solutions was investigated. Surface analysis using scanning electron microscopy (SEM) exhibited a porous structure, while Fourier-transform infrared spectroscopy (FTIR) identified distinct functional groups on the surface. The point of zero charge (PZC), determined at 6.95, revealed the adsorbent’s surface chemistry. Impressively, the synthesized carbosorbent exhibited significant adsorption capacities of 23.08 mg.g-1 for Cr(III) and 24.84 mg.g-1 for Cr(VI) under optimal conditions. The Langmuir isotherm model illustrated a monolayer adsorption mechanism aligned with the pseudo-second-order kinetic model, confirming chemisorption. Thermodynamic analysis disclosed favorable and spontaneous chromium adsorption. Negative ΔG° values affirmed the spontaneity, while the exothermic nature of the process was signified by the positive ΔH° value, indicating heat release. Increased randomness at the solid-liquid interface, indicated by the positive ΔS° value, underscored the enhanced affinity between the adsorbent and adsorbate. This study exemplifies the potential of the vapor-activated carbosorbent as an efficient and sustainable remedy for chromium-contaminated water bodies.
اظهر المزيد [+] اقل [-]Need for an Evolved Groundwater Justice in Rural Areas of Uttar Pradesh, India
2024
V. S. Tari, N. Siddiqui, D. Rathi, N. N. Siddiqui and D. K. Wahyuni
As groundwater is the primary element of life, countries all over the world are experimenting with legal reforms. The degree to which law reforms combine justice and sustainability is a crucial question. In response to this question, the present article focuses on a case study of Uttar Pradesh, India. Our response is based on a content analysis of the Uttar Pradesh Groundwater (Management and Regulation) Act, 2019, and the Uttar Pradesh Groundwater (Management and Regulation) Rules, 2020. Three conclusions emerged from our investigation. First, the 2019 Groundwater Act and the 2020 Draft Groundwater Rules are primarily motivated by concerns about resource sustainability, particularly in areas where the water table is steadily declining. Still, neither the 2019 Groundwater Act nor the 2020 Draft Groundwater Rules propose any proactive groundwater justice measures. Second, we suggest that some locally defined basic elements are critical in supporting sustainability and – to a lesser extent – groundwater justice. These characteristics include a community’s ability to (1) recognize a crisis and show a willingness to address it; (2) establish a rule-bound community groundwater resource; (3) demonstrate leadership and a sense of community; and (4) make use of awareness, information, and knowledge. Our third conclusion is that there is a need for community practices and state-led groundwater law to co-evolve; this co-evolution has the potential to create groundwater arrangements that support both groundwater justice and sustainability.
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