In Nigeria irrigated agriculture is an important tool for economic growth, food security, and poverty reduction during dry periods of rain-fed agriculture. The concentration and composition of dissolved constituents in water determines its quality for irrigation use. Water quality studies strongly suggest that agriculture is a leading source of water quality problems, due to pesticides and other agro-inputs, widely used by farmers to improve agricultural productivity. Poor quality irrigation water would therefore obviously affect soil quality and crop productivity. This study was carried out in 2015 to assess the presence of metals and physical properties of water, used for irrigation in Kwara state, Nigeria. Samples were randomly collected from thirty irrigation sources in three senatorial zones of Kwara State. The samples were analyzed for the presence of metals and water quality parameters, using standard procedures. Results showed that the highest concentration of Sulphate (7.0mg/L), Nitrate (8.9mg/L), Sodium (31.6mg/L), Calcium (3.1mg/L), and Magnesium (0.7) ions were within acceptable limits. The Sodium Adsorption Ratio, an indicator for water suitability in agricultural irrigation as well as a standard diagnostic parameter for the sodicity hazard of a soil, was significantly the highest (22.7) in Kwara North. Results of the study point to the need for an effective irrigation water quality assessment to curb nonpoint source pollution that could be caused by improper use of chemicals and pesticides by farmers.

This work investigates the possibility of using constructed wetland system for the management of municipal wastewaters with reuse strategies for the irrigation of landscapes in Ouled Djellal city of Biskra, Algeria. The design of this system was based on the characteristics (volume and physico-chemical properties) of wastewaters and the urban plan of the studied city. Results showed that studied effluent is easily biodegradable with COD/BOD5 of  1.84 (< 3), BOD5 (325 - 365 mg/L), COD (620-644 mg/L) and TSS (120-250mg/l). The peak of raw wastewater flow was found to be 32.4 m3 /h, which was used for the calculation of drip network for the landscape irrigation. The selected variant for the configuration of the CW system is HF-VF-HF, which occupies an area of 11.580 m2 and will reduce significantly the water pollution. The treated wastewater will be reused for the irrigation of landscapes via the dimensioned drip network. Results of this study showed that the proposed design for the system (treatment and reuse) would be effective in reducing pollution in the urban environment by ensuring possibility of the reuse of the treated water for irrigation. This gives also a great opportunity for using this strategy in small neighborhoods in other cities.

Batiaghata Upazila, Khulna District in south-west coastal region of Bangladesh is the mostly saline affected area, where agriculture activities are mainly dependent on rainfall. 23 water samples from surface water and shallow tube well (STW) were collected in the monsoon season and analyzed for physico-chemical properties to classify them according to salinity hazard. Electrical Conductivity (EC) of both surface and groundwater samples were slightly higher than that of acceptable limit ( Ca2+ > Mg2+ > K+ in both surface and groundwater while the anions trend in both surface and groundwater of the study area were Cl¯ > SO42¯ > PO43¯. EC and TDS showed high positive correlation with Na+, K+ and Ca2+ with Cl¯ as confirmed from Correlation Matrix and Principal Component Analysis (PCA). Most of the STW water samples compared to the surface water had higher Soluble Sodium Percentage (SSP) values while Sodium Adsorption Ratio (SAR) indicated the surface water and ground water with low sodium hazard. The Kelly’s ratio of STW water is more subjected to sodium hazard compared to surface water in the study area.

Little is known about the occurrence of emerging pollutants (EPs) in waters in the Middle East and North Africa (MENA) region despite the extensive use of low-quality water there. Available data dealing with the sources, occurrence and removal of EPs within the MENA region in different categories of water is collected, presented and analyzed in this literature review. According to the collected database, the occurrence and removal efficiency of EPs in the water matrix in the MENA region is available, respectively, for 13 and six countries of the 18 in total; no available data is registered for the rest. Altogether, 290 EPs have been observed in different water matrices across the MENA countries, stemming mainly from industrial effluents, agricultural practices, and discharge or reuse of treated wastewater (TWW). Pharmaceutical compounds figure among the most frequently reported compounds in wastewater, TWW, surface water, and drinking water. Nevertheless, pesticides are the most frequently detected pollutants in groundwater. Worryingly, 57 cases of EPs have been reported in different fresh and drinking waters, exceeding World Health Organization (WHO) and European Commission (EC) thresholds. Overall, pharmaceuticals, organic compounds, and pesticides are the most concerning EP groups. The review revealed the ineffectiveness of treatment processes used in the region to remove EPs. Negative removals of some EPs such as carbamazepine, erythromycin, and sulfamethoxazole were recorded, suggesting their possible accumulation or release during treatment. This underlines the need to set in place and strengthen control measures, treatment procedures, standards, and policies for such pollutants in the region.

One of the fundamental sustainable development goals has been recognized as having access to clean water for drinking purposes. In the Anthropocene era, rapid urbanization put further stress on water resources, and associated groundwater contamination expanded into a significant global environmental issue. Natural arsenic and related water pollution have already caused a burden issue on groundwater vulnerability and corresponding health hazard in and around the Ganges delta. A field based hydrogeochemical analysis has been carried out in the elevated arsenic prone areas of moribund Ganges delta, West Bengal, a part of western Ganga- Brahmaputra delta (GBD). New data driven heuristic algorithms are rarely used in groundwater vulnerability studies, specifically not yet used in the elevated arsenic prone areas of Ganges delta, India. Therefore, in the current study, emphasis has been given on integration of heuristic algorithms and random forest (RF) i.e., “RF-particle swarm optimization (PSO)”, “RF-grey wolf optimizer (GWO)” and “RF-grasshopper optimization algorithm (GOA)”, to identify groundwater vulnerable zones on the basis of field based hydrogeochemical parameters. In addition, correspondence health hazard of this area was assessed through human health hazard index. The spatial distribution of groundwater vulnerability revealed that middle-eastern and north-western part of the study area covered by very high and high, whereas central, western and south-western part are covered by very low and low vulnerability zones in outcomes of all the applied models. The evaluation result indicates that RF-GOA (AUC = 0.911) model performed the best considering testing dataset, and thereafter RF-GWO, RF-PSO and RF with AUC value is 0.901, 0.892 and 0.812 respectively. Findings also revealed the groundwater in this study region is quite unfavorable for drinking and irrigation purposes. The suggested models demonstrate their usefulness in foretelling sustainable groundwater resource management in various deltaic regions of the world through taking appropriate measures by policy-makers.

Excessive enrichment of fluoride threatens ecological stability and human health. The high-fluoride groundwater in the Chagan Lake area has existed for a long time. With the land consolidation and irrigation area construction, the distribution and migration process of fluoride have changed. It is urgent to explore the evolution of fluoride under the dual effects of nature and human. Based on 107 groundwater samples collected in different land use periods, hydrogeochemistry and isotope methods were combined to explore the evolution characteristics and hydrogeochemical processes of fluoride in typical high-fluoride background area and elucidate the impact of anthropogenic activities on fluoride migration. The results indicate that large areas of paddy fields are developed from saline-alkali land, and its area has increased by nearly 30%. The proportion of high-fluoride groundwater (>2 mg/L) has increased by nearly 10%, mainly distributed in the new irrigation area. Hydrogeochemical processes such as dissolution of fluorine-containing minerals, precipitation of carbonate minerals and exchange of Na⁺, Ca²⁺ on the water-soil interface control the enrichment of fluoride. The groundwater d-excess has no obvious change with the increase of TDS, and human activities are one of the reasons for the increase of fluoride. The concentration of fluoride is diluted due to years of diversion irrigation in old irrigation area, whereas the enrichment of δ²H, δ¹⁸O and Cl⁻ in new irrigation area indicates that the vertical infiltration of washing alkali and irrigation water brought fluoride and other salts to groundwater. Fertilizer and wastewater discharges also contribute to the accumulation of fluoride, manifesting as co-increasing nitrate and chloride salts. The results of this study provide a new insight into fluoride migration under anthropogenic disturbance in high-fluoride background areas.

Arsenic (As) exposure is a global public health concern affecting millions worldwide and stems from drinking water and foods containing As. Here, we assessed how agronomic practices and postharvest fermentation techniques influence As concentrations in rice bran, and calculated health risks from consumption. A global suite of 53 rice brans were tested for total As and speciation. Targeted quantification of inorganic As (iAs) concentrations in rice bran were used to calculate Target Hazard Quotient (THQ) and Lifetime Cancer Risk (LCR) across the lifespan. Mean iAs was highest in Thailand rice bran samples (0.619 mg kg⁻¹) and lowest in Guatemala (0.017 mg kg⁻¹) rice bran samples. When comparing monosodium-methanearsonate (MSMA) treated and the Native-soil counterpart under the irrigation technique Alternate Wetting and Drying (AWD) management, the MSMA treatment had significantly higher total As (p = 0.022), and iAs (p = 0.016). No significant differences in As concentrations were found between conventional and organic production, nor between fermented and non-fermented rice bran. Health risk assessment calculations for the highest iAs-rice bran dosage scenario for adults, children and infants exceeded THQ and LCR thresholds, and LCR was above threshold for median iAs-rice bran. This environmental exposure investigation into rice bran provides novel information with food safety guidance for an emerging global ingredient.

Potato (Solanum tuberosum L.) production in irrigated coarse-textured soils requires intensive nitrogen (N) fertilization which may increase reactive N losses. Biological soil additives including N-fixing microbes (NFM) have been promoted as a means to increase crop N use efficiency, though few field studies have evaluated their effects, and none have examined the combined use of NFM with microbial inhibitors. A 2-year study (2018–19) in an irrigated loamy sand quantified the effects of the urease inhibitor NBPT, the nitrification inhibitor DMPSA, NFM, and the additive combinations DMPSA + NBPT and DMPSA + NFM on potato performance and growing season nitrous oxide (N₂O) emissions and nitrate (NO₃⁻) leaching. All treatments, except a zero-N control, received diammonium phosphate at 45 kg N ha⁻¹ and split applied urea at 280 kg N ha⁻¹. Compared with urea alone, DMPSA + NBPT reduced NO₃⁻ leaching and N₂O emissions by 25% and 62%, respectively, and increased crop N uptake by 19% in one year, although none of the additive treatments increased tuber yields. The DMPSA and DMPSA + NBPT treatments had greater soil ammonium concentration, and all DMPSA-containing treatments consistently reduced N₂O emissions, compared to urea-only. Use of NBPT by itself reduced NO₃⁻ leaching by 21% across growing seasons and N₂O emissions by 37% in 2018 relative to urea-only. In contrast to the inhibitors, NFM by itself increased N₂O by 23% in 2019; however, co-applying DMPSA with NFM reduced N₂O emissions by ≥ 50% compared to urea alone. These results demonstrate that DMPSA can mitigate N₂O emissions in potato production systems and that DMPSA + NBPT can reduce both N₂O and NO₃⁻ losses and increase the N supply for crop uptake. This is the first study to show that combining a nitrification inhibitor with NFM can result in decreased N₂O emissions in contrast to unintended increases in N₂O emissions that can occur when NFM is applied by itself.

Detailed, high resolution time-series observations were performed to investigate sources, diel cycling, natural attenuation, and loadings of dissolved trace metals/metalloids in a subtropical headwater stream draining intensive horticulture in Australia. A transect of ∼3 km away from the source (farms) showed >75% reduction in concentration and loads of most trace elements. Mercury and arsenic had elevated loads downstream relative to other elements. Hourly time-series sampling revealed elevated creek discharge at night, accompanied by elevated nickel, selenium, copper, and mercury loads. Inputs from groundwater or treated sewage used for irrigation within the catchment are likely sources. Groundwater bore and treated sewage samples were highly contaminated with either zinc, copper, or mercury. Comparisons of daily and hourly samples indicated common sampling strategies can underestimate horticultural contaminant loadings. Load estimates for mercury and copper derived from hourly samples were 1.6- to 7- fold greater than loads from daily sample data collected over 79 days with varying rainfall. These high contaminant concentrations and loads are of concern to food products receiving irrigation and protected waterbodies downstream.