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Phosphorus removal by ferrous iron and lime
1971
Alvord, E. Thomas
Spent pickle liquor, as a source of ferric ion, was added to primary treatment facilities and found to be effective in removing more than 60% of the phosphorus contained in the sewage. When advanced means for more complete removal of the insolubilized phosphates are available, removals in excess of 90% are indicated. In addition, overall suspended solids removals averaged 61.5% and BOD and COD removals averaged 61.6 and 55.3 percent during a 23 month test period. Required iron dosage ranged from the theoretical minimum of 2.7 to a maximum of approximately 3.1 weights of ferrous iron per weight of phosphorus. The weight increase in sludge solids due to chemical precipitation of phosphorus was 100 lbs/million gallons/mg/liter of phosphorus in the influent. Total costs for treating a raw sewage containing 13 mg/l phosphorus are given.
اظهر المزيد [+] اقل [-]Limestone treatment of rinse waters from hydrochloric acid pickling of steel
1971
Phosphorus removal with pickle liquor in an activated sludge plant
1971
Leary, Raymond D.
Hot waste pickle liquor (ferrous sulfate) as an iron source was successful in precipitating phosphorus from solution in a 115 mgd East Plant of Milwaukee's Jones Island Activated Sludge Wastewater Treatment Plant. An 85 mgd section of the plant receiving the same influent was operated as a control. The East Plant with iron addition, achieved 91.3% removals (0.70 mg/1 P effluent residual), while the control West Plant removed 83.1% (1.4 mg/1 P residual). Comparison of efficiencies of purification, pH, alkalinity, and microscopic examinations of the sludge microorganism indicated that the addition of unneutralized waste pickle liquor did not adversely affect purification processes.
اظهر المزيد [+] اقل [-]Brass wire mill process changes and waste abatement, recovery and reuse
1971
Lancy, Leslie E. | Forbes, Charles A.
The report describes process changes and waste treatment, recovery, and reuse facilities installed by Volco Brass and Copper Company, Kenilworth, New Jersey. The plant produces 75 tons of wire per day. An electrolytic system was installed to recover copper from the spent primary pickle solution and to regenerate the sulfuric acid for reuse. A hydrogen peroxide bright pickle replaced the chromate and fluoride bright pickles previously used. Copper from the bright pickle is also recovered in the electrolytic system. The electrolytic copper is reused on location in casting. An integrated copper treatment system was installed to treat bright pickle drag-out. Sludge from the integrated system is recovered for sale. Rinse water consumption was reduced from 150 gpm to 10 gpm. Former discharges of chromium, ammonium, and fluoride ions have been eliminated. Cost and operating data and effluent analyses are presented.
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