In indoor air, terpene-ozone reactions can form secondary organic aerosols (SOA) in a transient process. ‘Real world’ measurements conducted in a furnished room without air conditioning were modelled involving the indoor background of airborne particulate matter, outdoor ozone infiltrated by natural ventilation, repeated transient limonene evaporations, and different subsequent ventilation regimes. For the given setup, we disentangled the development of nucleated, coagulated, and condensed SOA fractions in the indoor air and calculated the time dependence of the aerosol mass fraction (AMF) by means of a process model. The AMF varied significantly between 0.3 and 5.0 and was influenced by the ozone limonene ratio and the background particles which existed prior to SOA formation. Both influencing factors determine whether nucleation or adsorption processes are preferred; condensation is strongly intensified by particulate background. The results provide evidence that SOA levels in natural indoor environments can surpass those known from chamber measurements. An indicator for the SOA forming potential of limonene was found to be limona ketone. Multiplying its concentration (in μg/m³) by 450(±100) provides an estimate of the concentration of the reacted limonene. This can be used to detect a high particle formation potential due to limonene pollution, e.g. in epidemiological studies considering adverse health effects of indoor air pollutants.

Initiatives to displace petroleum and climate change mitigation have driven a recent increase in space heating with biomass combustion. However, there is ample evidence that biomass combustion emits significant quantities of health damaging pollutants. We investigated the near-source micro-environmental air quality impact of a biomass-fueled combined heat and power system equipped with an electrostatic precipitator (ESP) in Syracuse, NY. Two rooftop sampling stations with PM2.5 and CO2 analyzers were established in such that one could capture the plume while the other one served as the background for comparison depending on the wind direction. Four sonic anemometers were deployed around the stack to quantify spatially and temporally resolved local wind patterns. Fuel-based emission factors were derived based on near-source measurement. The Comprehensive Turbulent Aerosol Dynamics and Gas Chemistry (CTAG) model was then applied to simulate the spatial variations of primary PM2.5 without ESP. Our analysis shows that the absence of ESP could lead to an almost 7 times increase in near-source primary PM2.5 concentrations with a maximum concentration above 100 μg m−3 at the building rooftop. The above-ground “hotspots” would pose potential health risks to building occupants since particles could penetrate indoors via infiltration, natural ventilation, and fresh air intakes on the rooftop of multiple buildings. Our results demonstrated the importance of emission control for biomass combustion systems in urban area, and the need to take above-ground pollutant “hotspots” into account when permitting distributed generation. The effects of ambient wind speed and stack temperature, the suitability of airport meteorological data on micro-environmental air quality were explored, and the implications on mitigating near-source air pollution were discussed.

A new vegetation modeling concept for Building and Environmental Aerodynamics wind tunnel investigations was developed. The modeling concept is based on fluid dynamical similarity aspects and allows the small-scale modeling of various kinds of vegetation, e.g. field crops, shrubs, hedges, single trees and forest stands. The applicability of the modeling concept was validated in wind tunnel pollutant dispersion studies. Avenue trees in urban street canyons were modeled and their implications on traffic pollutant dispersion were investigated. The dispersion experiments proved the modeling concept to be practicable for wind tunnel studies and suggested to provide reliable concentration results. Unfavorable effects of trees on pollutant dispersion and natural ventilation in street canyons were revealed. Increased traffic pollutant concentrations were found in comparison to the tree-free reference case.

There have been an increasing number of automobile vehicles in cities, so that newly developed residential areas are mostly designed with underground parking garages (UPGs). For naturally ventilated UPGs, the ventilation performance may be insufficient to discharge totally vehicle-induced pollutants out of the enclosed underground spaces, which consequently results in threats to residents' health. This study, therefore, aims at examining the patterns of pollutant concentrations in naturally ventilation UPGs as well as their sensitivities to traffic volume. In particular, the naturally ventilated UPGs’ weekday particulate matters (PM₂.₅ and PM₁₀), CO₂ and TVOC concentration as well as their relationships between traffic volume were quantitively evaluated based on field measurements in eight residential areas in Baoding, China. Results indicated that daily average PM₂.₅, PM₁₀, CO₂ and TVOC concentrations in studied UPGs were 105.81 μg/m³, 464.17 μg/m³, 571 ppm and 24 ppb, respectively. The PM₂.₅ concentrations in UPGs were slightly higher than that in ambient environments, while the PM₁₀ concentrations in UPGs were significantly higher. Furthermore, both PM₁₀ and TVOC concentrations in UPGs were in significant relationships with traffic volume at the p < 0.01 level, while the concentration of UPG PM₂.₅ generally exhibited a significant correlation (p < 0.01) with that of the ambient. Nevertheless, a combination of traffic volume, the ambient and accumulative effect was much better to explain the hourly PM₁₀ concentration in UPGs. These findings will be conducive to instruct engineers with fundamental knowledge of UPG ventilation design.

This research investigated the use of two relatively cost-effective devices for determining NH3 concentrations in naturally ventilated (NV) dairy barns including an Ogawa passive sampler (Ogawa) and a passive flux sampler (PFS). These samplers were deployed adjacent to sampling ports of a photoacoustic infrared multigas spectroscope (INNOVA), in a NV dairy barn. A 3-day deployment period was deemed suitable for both passive samplers. The correlations between concentrations determined with the passive samplers and the INNOVA were statistically significant (r = 0.93 for Ogawa and 0.88 for PFS). Compared with reference measurements, Ogawa overestimated NH3 concentrations in the barn by ∼14%, while PFS underestimated NH3 concentrations by ∼41%. Barn NH3 emission factors per animal unit (20.6–21.2 g d⁻¹ AU⁻¹) based on the two passive samplers, after calibration, were similar to those obtained with the reference method and were within the range of values reported in literature.

This study investigated levels and possible determinants of polycyclic aromatic hydrocarbons (PAHs) in settled house dust of urban dwellings with preschool–aged children in Nanjing, China. The possible neurodevelopmental effects of house–dust PAHs on the children were also investigated. Settled house dust was collected from 203 urban houses. Fifteen PAHs were measured using an HPLC with a fluorescence detector and wavelength programming. The Child Behavior Checklist and the Gesell Development Inventory were used to evaluate the overall development of the children. PAHs were detected in settled house dust of >90% of houses, where high molecular weight PAHs predominated. Most PAHs with two or three rings were found at significantly higher levels in indoor compared with outdoor dust. PAH isomeric ratios showed that PAHs with four or more rings might be derived from outdoor coal burning sources. Naphthalene was found at lower concentrations in houses with more hours of natural ventilation, while pyrene, chrysene (Chr) and benzo[k]fluoranthene (BkF) were present at higher concentrations in these houses. A higher floor level correlated with lower levels of PAHs, especially those with four or more rings, while older houses had higher PAH levels. Benzo[a]pyrene (BaP) and indeno[1,2,3–cd]pyrene levels were positively associated with most behavioral problem scores. Higher BaP and benzo[g,h,i]perylene levels showed lower Gesell language development quotient (DQs), and higher Chr and BkF were associated with lower Gesell social skill DQs. In conclusion, 15 PAHs are ubiquitous in urban settled house dust, where outdoor coal burning and indoor cooking oil fumes are the two main sources of PAHs in Nanjing, China. Natural ventilation, floor level and residence age potentially influence house dust PAH levels. The potential adverse effect of postnatal exposure to PAHs on the behavior and neurodevelopment of preschool–aged children requires follow up in larger studies.

The indoor environment of schools where children stay for long periods of time is a matter of primary concern due to the vulnerability and sensibility of children to air pollutant exposure. The aims of this study were to characterize the indoor air quality of elementary schools in Seoul, Korea, to compare the indoor levels according to the surrounding environments and year of remodeling. The air pollutants, including particle matter (PM10), nitrogen dioxide (NO2), carbon monoxide (CO), carbon dioxide (CO2), total bacteria count (TBC), total volatile organic compounds (TVOC) and formaldehyde (HCHO), were sampled during autumn from classrooms and laboratories at 116 elementary schools employing natural ventilation. The schools were selected based on their surrounding environments: surrounded by buildings (SB), roadways (RW), and mountains (MT). The indoor air quality measured at elementary schools in Seoul, Korea showed generally low levels of pollutants due to low occupancy and adequate ventilation and the indoor levels of PM10 and TBC in schools near roadways were significantly lower than other surrounding environments due to dispersion of pollutants, without obstruction by buildings and mountains. TVOC and HCHO concentrations of schools remodeled within a year were significantly higher. Therefore, suitable management for school building characteristics is needed.

Concentrations of naturally occurring radioactive gas can be high in caves and mines, and it has been shown that releases of radon (²²²Rn) to the outside environment through ventilation can be large. We assess airflow and associated activity concentrations of thoron (²²⁰Rn) and progeny (TnP) being released through a drainage pipe from an old mine-complex situated in thorium-rich bedrock. Outdoor thoron concentrations in this area have been thought to arise solely from thoron exhalation from the ground. However, thoron concentrations in outwards airflow in the drainage pipe range from 25 000 Bq m⁻³ to 42 000 Bq m⁻³ and discharges can in summer be as high as 1 GBq d⁻¹. The drainage pipe can be considered as a point source adding to exhalation from the soil and deposits of waste rock in the area. Statistical analyses including meteorological data suggest that outdoor temperature is the main factor affecting this airflow and that ventilation of these mines resembles chimney ventilation, but other weather variables may also contribute. During summer with warm outdoor temperatures, colder and denser air within the mines escapes through the drainage pipe, which is located on low ground. In winter, when outdoor temperatures are lower than those within the mines, the direction of airflow in the drainage pipe is inwards into the mines, while air escapes upwards and outwards through larger mine openings located on higher ground. Statistical outliers indicate Venturi effects by strong winds and syringe effects by internal water level.

Additive manufacturing is an innovative technology that allows the production of three-dimensional objects replicating digital models. The aim of this study was to identify whether the use of this technology in a room without mechanical ventilation system may pose a health risk to its users due to the emission of chemical compounds and fine particles. Measurements were conducted in a furnished space with natural ventilation only, during additive manufacturing on a fused deposition modeling printer with 9 different filaments. Both chemicals and particles were sampled. Volatile organic compounds and phthalic acid esters were determined by gas chromatography–mass spectrometry detection. Carbonyl compounds were determined using the high-performance liquid chromatography with diode-array detection method. Fine particle emission studies were carried out using a DiSCmini particle counter (Testo). In the air samples, numerous chemical substances were identified including both the monomers of the individual materials used for printing such as styrene and other degradation products (formaldehyde, toluene, xylenes). Moreover, 3D printing process released particles with modal diameters ranging from 22.1 to 106.7 nm and increased the number concentration of particles in the workplace air. The results of analyses, depending on the type of material applied, showed the presence of particles and chemical substances in the working environment that may pose a risk to human health. Most of the identified substances can be harmful when inhaled and irritating to eyes and skin.

The study of the fungal community composition in house dust is useful to assess the accumulative exposure to fungi in indoor environments. The objective of this research was to characterize the fungal diversity of house dust and its association with the environmental conditions of bedrooms. For this, the dust was collected from 41 bedrooms of children between the ages of 8 and 9 with a family history of asthma, residents of Havana, Cuba. The fungal content of each sample was determined by two methods: plate culture with malt extract agar and by direct microscopy. An ecological analysis was carried out from the fungal diversity detected. To describe the factors associated with the fungi detected, bivariate logistic regression was used. Through direct microscopy, between 10 and 2311 fragments of hyphae and spores corresponding mainly to Cladosporium, Coprinus, Curvularia, Aspergillus/Penicillium, Xylariaceae, and Periconia were identified. Through the culture, 0–208 CFU were quantified, where Aspergillus, Cladosporium, and Penicillium predominated. The culturability evidenced the differences between the quantification determined by both methods. A positive relationship was found between the type of cleaning of the furniture, the presence of trees in front of the bedroom, indoor relative humidity, indoor temperature, the presence of air conditioning, and natural ventilation with specific spore types and genera. The use of two different identification methods allowed to detect a greater fungal diversity in the residences evaluated. Monitoring the exposure to these fungal allergens in childhood can help to prevent sensitization in the allergic child, the development of asthma, and other respiratory diseases.