A large anthropogenic source of mercury pollution is mercury-dependent artisanal and small-scale gold mining (ASGM). Thabeikkyin Township is a small-scale gold mining township located in Pyin Oo Lwin District in the Mandalay Region, Myanmar. The villages of Thabeikkyin Township engage in gold ore crushing, screening, refining, and other mining activities for a living. Miners in this area commonly use mercury for gold recovery by heating amalgam at their homes, gold shops, on the street, and near the riverbank. The evaporated mercury is released into the atmosphere during the heating process and then transported and deposited in the surrounding environments, resulting in the mercury pollution of air, water, soil, etc. To assess atmospheric mercury pollution, a preliminary study on the environmental mercury contamination from ASGM was conducted in Thabeikkyin Township. High mercury concentrations were observed in plant samples collected near the refining sites, ranging 0.33–6.51 ug/g, compared with 0.02 ug/g in Wet Thay Village, where no mercury use was reported. Correlation coefficients between Hg and other heavy metals showed that no heavy metal concentration significantly correlated with that of Hg. The results indicated that the atmospheric environment in the ASGM area of Thabeikkyin Township was contaminated with mercury originating from ASGM, which could very likely deteriorate the health of surrounding residents.