Antimicrobial nanomaterials provide numerous opportunities for the synthesis of next-generation sustainable water disinfectants. Using the keywords graphene and water disinfection and graphene antibacterial activity, a detailed search of the Scopus database yielded 198 and 1433 studies on using graphene for water disinfection applications and graphene antibacterial activity in the last ten years, respectively. Graphene family nanomaterials (GFNs) have emerged as effective antibacterial agents. The current innovations in graphene-, graphene oxide (GO)-, reduced graphene oxide (rGO)-, and graphene quantum dot (GQD)-based nanocomposites for water disinfection, including their functionalization with semiconductor photocatalysts and metal and metal oxide nanoparticles, have been thoroughly discussed in this review. Furthermore, their novel application in the fabrication of 3D porous hydrogels, thin films, and membranes has been emphasized. The physicochemical and structural properties affecting their antibacterial efficiency, such as sheet size, layer number, shape, edges, smoothness/roughness, arrangement mode, aggregation, dispersibility, and surface functionalization have been highlighted. The various mechanisms involved in GFN antibacterial action have been reviewed, including the mechanisms of membrane stress, ROS-dependent and -independent oxidative stress, cell wrapping/trapping, charge transfer, and interaction with cellular components. For safe applications, the potential biosafety and biocompatibility of GFNs in aquatic environments are emphasized. Finally, the current limitations and future perspectives are discussed. This review may provide ideas for developing efficient and practical solutions using graphene-, GO-, rGO-, and GQD-based nanocomposites in water disinfection by rationally employing their unique properties.

Two areas in central-southern Italy Land of Fires in Campania and Valley of Sacco river in Lazio are known to be contaminated sites, the first due to illegal fly-tipping and toxic fires, and the second due to an intensive industrial exploitation done by no-scruple companies and crooked public administration offices with dramatic consequences for environment and resident people. The work is intended to contribute to Human BioMonitoring (HBM) studies conducted in these areas on healthy young male population by a semiconductor gas sensor array trained by SPME-GC/MS. Human semen, blood and urine were investigated. The fingerprinting of the Volatile Organic Compounds (VOCs) by a gas sensors system allowed to discriminate the different contamination of the two areas and was able to predict the chemical concentration of several VOCs identified by GC/MS.

The photocatalytic activity of semiconducting silver carbonate was restricted by the lower stability and fast recombination rate of photogenerated electron–hole pairs. Sulfur-doped graphene oxide (SGO) is used as a cocatalyst for improving the photocatalytic activity of Ag₂CO₃ by reducing the recombination rate. A simple precipitation method was used for the modification of silver carbonate. The chemical, physical, optical, and electrochemical properties of the modified photocatalyst was characterized by XRD, SEM, TEM, UV–vis DRS, XPS, CV, impedance, and amperometry. The fabricated SGO-Ag₂CO₃ composite was successfully degraded various organic pollutants such as methylene blue (MB), rhodamine B(RhB), methyl orange (MO), tartrazine, and thiram with augmented mineralization. The optimization of weight percentage of the developed binary composite with 0.5% SGO-Ag₂CO₃ showed enhanced photocatalytic degradation and followed pseudo-first-order kinetics with rate constant 0.126. More than 90% of degradation efficiency of the pollutants within a short time promises the binary heterostructure for future industrial applications. The excellent stability and reproducibility of the composite opened a new route in the treatment of wastewater.

The disposal of dye-contaminated wastewater is a major concern around the world for which a variety of techniques are used for its treatment. The photocatalytic treatment of dye-contaminated wastewater is one of the treatment methods. Semiconductor-assisted photocatalytic treatment of dye-contaminated wastewater has gained pronounced attention recently. This review outlines the recent advancements in the photocatalytic treatment of dye-contaminated wastewater. The photocatalytic degradation of dyes follows three types of mechanisms: (1) dye sensitization through charge injection, (2) indirect dye degradation through oxidation/reduction, and (3) direct photolysis of dye. Several experimental parameters like initial concentration of dyes, pH, and catalyst dosage significantly affect the photocatalytic degradation of dyes. The photocatalytic materials can be categorized into three generations. The single-component (e.g., ZnO, TiO₂) and multiple component semiconductor metal oxides (e.g., ZnO–TiO₂, Bi₂O₃–ZnO) are categorized as first-generation and second-generation photocatalysts, respectively. The photocatalysts dispersed on an inert solid substrate (e.g., Ag–Al₂O₃, ZnO–C) are classified as third-generation photocatalysts. Finally, we reviewed the challenges that affect the photocatalytic degradation of dyes.

Dye-sensitized solar cells (DSSCs) were devised with the sensitizers prepared from the leaves and flowers of Amaranthus cruentus. Fresh and dried leaves were employed for extracting the dye sensitizers. Acetone, ethanol, and deionized water were used as solvents for the extraction process. A sum of nine dyes was prepared. For all the extracted dyes, spectroscopic studies (UV–visible & FTIR) were performed to ensure that the dyes are suitable to be used as sensitizers for DSSC. XRD and SEM were recorded for the TiO₂ paste used. Nine DSSCs were fabricated with the extracted dyes as sensitizers, TiO₂ as semiconductor oxide, I⁻/I³⁻ as electrolyte, and graphene-coated FTO as counter electrode. J-V characterization study was done for each cell showed that the cell with dye taken from the fresh leaves using acetone exhibited the highest efficiency of 0.816%. It was noted that these cells recorded higher efficiency than the previously reported works with dyes taken from Amaranthus red.

Semiconductor photocatalysis technology has shown great potential in the field of organic pollutant removal, as it can use clean and pollution-free solar energy as driving force. The discovery of silver phosphate (Ag₃PO₄) is a major breakthrough in the field of visible light responsive semiconductor photocatalysis due to its robust capacity to absorb visible light < 520 nm. Furthermore, the holes produced in Ag₃PO₄ under light excitation possess a strong oxidation ability. However, the strong oxidation activity of Ag₃PO₄ is only achieved in the presence of electron sacrifice agents. Otherwise, photocorrosion would greatly reduce the reuse efficiency of Ag₃PO₄. This review thus focuses on the structural characteristics and preparation methods of Ag₃PO₄. Particularly, the recent advances in noble metal deposition, ion doping, and semiconductor coupling, as well as methods of magnetic composite modification for the improvement of catalytic activity and recycling efficiency of Ag₃PO₄-based catalysts, were also discussed, and all of these measures could enhance the catalytic performance of Ag₃PO₄ toward organic pollutants degradation. Additionally, some potential modification methods for Ag₃PO₄ were also proposed. This review thus provides insights into the advantages and disadvantages of the application of Ag₃PO₄ in the field of photocatalysis, clarifies the photocorrosion essence of Ag₃PO₄, and reveals the means to improve photocatalytic activity and stability of Ag₃PO₄. Furthermore, it provides a theoretical and methodological basis for studying Ag₃PO₄-based photocatalyst and also compiles valuable information regarding the photocatalytic treatment of organic polluted wastewater.

Understanding the graphene/semiconductor/metal interactions is crucial to design innovative photocatalytic materials with efficient photocatalytic activity for environmental cleanup applications. SrTiO₃ on reduced graphene oxide (rGO) with various graphene contents was successfully synthesized in this study utilizing a simple hydrothermal method, followed by decorating the surface with Ag particles by using the photodeposition process. Under UV–visible light irradiation, the resulting composites were tested for their improved photocatalytic activity to decompose methylene blue (MB). The prepared photocatalysts were characterized by XRD, SEM, EDX, DLS, FT-IR, Raman spectroscopy, and DRS. First-principle density functional theory calculations (DFT) were also carried out by using the generalized gradient approximation (GGA) and PBE functional with the addition of on-site Coulomb correction (GGA + U). The obtained SrTiO₃/rGO@Ag composites showed great improvement in the photocatalytic performances over pristine SrTiO₃. For the degradation reaction of MB, SrTiO₃/rGO₂₀%@Ag₄% composites yielded the best photocatalytic activity with efficacy reach 94%, which was also shown that it could be recycled up to four times with nearly unchanged photocatalytic activity.

Aryl-iodonium salts are utilized as photoacid generators (PAGs) in semiconductor photolithography and other photo-initiated manufacturing processes. Despite their utilization and suspected toxicity, the fate of these compounds within the perimeter of semiconductor fabrication plants is inadequately understood; the identification of photolithography products is still needed for a comprehensive environmental impact assessment. This study investigated the photolytic transformation of a representative iodonium PAG cation, bis-(4-tert-butyl phenyl)-iodonium, under conditions simulating industrial photolithography. Under 254-nm irradiation, bis-(4-tert-butyl phenyl)-iodonium reacted rapidly with a photolytic half-life of 39.2 s; different counter ions or solvents did not impact the degradation kinetics. At a semiconductor photolithography-relevant UV dosage of 25 mJ cm⁻², 33% of bis-(4-tert-butyl phenyl)-iodonium was estimated to be transformed. Six aromatic/hydrophobic photoproducts were identified utilizing a combination of HPLC–DAD and GC–MS. Selected photoproducts such as tert-butyl benzene and tert-butyl iodobenzene had remarkably higher acute microbial toxicity toward bacterium Aliivibrio fischeri compared to bis-(4-tert-butyl phenyl)-iodonium. Octanol–water partition coefficients estimated using the Estimation Programs Interface Suite™ indicated that the photoproducts were substantially more hydrophobic than the parent compound. The results fill a critical data gap hindering the environmental impact assessment of iodonium PAGs and provide clues on potential management strategies for both iodonium compounds and their photoproducts.

It is necessary to effectively separate photocatalytic materials from water bodies and reuse catalysts for industrial wastewater treatment. Herein, a novel nanofiber membrane with enhanced light absorption and reusability of photocatalytic materials was prepared. The three-dimensional porous structure of the nanofibers helps the photocatalyst efficiently degrade pollutants. Specifically, a high-efficiency photocatalyst carrier with a nanofiber structure (PAN/PU/β-CD@Ag nanofiber membrane) was prepared by electrospinning and a simple silver plating process, and then ZnO NPs were synthesized in situ on the nanofiber membrane during the hydrothermal process. Under visible-light irradiation, the ZnO-loaded PAN/PU/β-CD@Ag nanofiber membranes exhibited excellent photocatalytic performance for the degradation of methylene blue (MB, 71.5%) and tetracycline hydrochloride (TCH, 70.5%). Additionally, a possible pathway of charge migration in this system was proposed. This design may provide a new idea for the preparation of visible-light photocatalytic nanofiber membranes and their treatments of wastewater containing dyes and hormones.

The materials showing multiple applications are appealing for their practical use and industrial production. To realize the suitable property for various applications, we have produced ZnS (sf-ZnS) and metal-doped ZnS nanoflakes (sf-m-ZnS; where m = Cu, Ni, Cd, Bi, or Mn) and correlated their activity with bandgap variation. We obtained all these materials via hexamethyldisilazane (HMDS)-assisted synthetic method without using any surfactants, polymers, or template molecules and characterized them thoroughly using various techniques. Photocatalytic, as well as antibacterial, activities of these materials showed their bifunctional utility. We have demonstrated the effect of doping and consequent extension of absorption band to the visible region and resultant improved photocatalytic activity under sunlight. Thus, the change in bandgap influenced their performance as photocatalysts. Among all materials produced, sf-Cd-ZnS provided superior results as a photocatalyst while degrading two organic pollutants—rhodamine B (RhB) and methylene blue (MB) in water. The antibacterial activity of sf-ZnS and sf-m-ZnS against Gram-positive bacteria, i.e., Staphylococcus aureus (S. aureus), was examined by the zone of inhibition method, wherein sf-Ni-ZnS showed maximum activity. The enhanced activity of these ZnS materials can be attributed to the free surface of nanoparticles without any capping by organic molecules, which provided an intimate interaction of inorganic semiconductor material with organic and biomolecules. Thus, we have demonstrated modification of properties both by bandgap tuning of materials and providing the opportunity for intimate interaction of materials with substrates. The photocatalytic activity and antibacterial action of metal-doped ZnS produced by our method exhibited their potential for environmental remediation, specifically water purification.